首页> 外国专利> WATER-BASED POLYVINYLIDENE FLUORIDE COATING AND PREPARATION METHOD THEREFOR

WATER-BASED POLYVINYLIDENE FLUORIDE COATING AND PREPARATION METHOD THEREFOR

机译:水性聚偏二氟乙烯涂层及其制备方法

摘要

Disclosed is a water-based polyvinylidene fluoride coating. The coating comprises the following components of raw materials in parts by weight: 40-60 parts of a modified polyvinylidene fluoride emulsion, 5-10 parts of an aqueous sodium alginate solution, 2-7 parts by weight of a curing agent, 15-35 parts of a pigment and a filler, 7-15 parts of an auxiliary, and 5-35 parts of a solvent, the modified polyvinylidene fluoride emulsion being subjected to graft modification with 2-hydroxyethyl methacrylate and oxyethylene methacrylate. The present invention selects the modified polyvinylidene fluoride emulsion grafted by 2-hydroxyethyl methacrylate and oxyethylene methacrylate to cause the polyvinylidene fluoride resin to have hydrophilic side bonds, so that the resin matrix is modified to possess amphiphilicity from the strong hydrophobicity of a pure PVDF resin. Furthermore, the present invention uses the modified polyvinylidene fluoride emulsion as a main film-forming material, supplemented by the aqueous sodium alginate solution to further improve the water solubility of the resin system, thereby obtaining a water-based polyvinylidene fluoride coating with comprehensive performance comparable to that of existing solvent-based fluorocarbon coatings.
机译:公开了一种水基聚偏二氟乙烯涂层。涂层包括以下重量份的原料组分:40-60份改性聚偏二氟乙烯乳液,5-10份藻酸钠水溶液,2-7重量份的固化剂,15-35重量份颜料的份量和填料,7-15份助剂和5-35份溶剂,改性聚偏二氟乙烯乳液与甲基丙烯酸酯和氧乙烯酯的2-羟乙基甲酯进行接枝改性。本发明选择由甲基丙烯酸甲酯和氧丙烯酸甲酯接枝的改性聚偏二氟乙烯乳液,使聚偏二氟乙烯树脂具有亲水侧键,使得树脂基质被修饰以具有纯PVDF树脂的强疏水性的两亲性。此外,本发明使用改性的聚偏二氟乙烯乳液作为主要成膜材料,由藻酸钠水溶液补充,以进一步改善树脂体系的水溶性,从而获得具有综合性能的水基聚偏二氟乙烯涂层到现有的溶剂型氟碳涂料中。

著录项

  • 公开/公告号WO2021036757A1

    专利类型

  • 公开/公告日2021-03-04

    原文格式PDF

  • 申请/专利权人 FOSHAN UNIVERSITY;

    申请/专利号WO2020CN107908

  • 申请日2020-08-07

  • 分类号C09D151;C09D151/04;C09D127/16;C09D127/12;C08F259/08;C08F220/20;

  • 国家 CN

  • 入库时间 2024-06-14 21:21:25

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