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Blended lithium calcium base grease

机译:混合锂钙基润滑脂

摘要

A lubricating grease composition comprises a mixture of two component greases, component (1) comprising a lubricating oil thickened to a grease consistency with a complex of a metal salt and a metal soap or of two or more metal salts and component (2) comprising a lubricating oil thickened to a grease consistency with a lithium soap optionally in admixture with other metal. The complex of component (1) may be (a) a soap-salt complex prepared from a metal soap of a C12-C30 carboxylic acid and a metal salt of a C1-C3 carboxylic acid; (b) a soap-salt complex prepared from a metal soap of a C12-C30 carboxylic acid, a metal salt of a C3-C10 carboxylic acid and a metal salt of acetic acid; or (c) a mixed salt complex prepared from a metal salt of a C7-C10 carboxylic acid and a metal salt of a C1-C3 carboxylic acid. Specified C1-C3 acids are formic, acetic, propionic and lactic acids, while C3-C10 acids mentioned are alkane monocarboxylic acids and glyceric, lactic, citric, benzoic, hydroxybenzoic, toluic, phthalic, terephthalic, furoic and thiophene carboxylic acids. The C7-C10 acids mentioned are alkane monocarboxylic acids, while the C12-C30 acids are saturated or unsaturated fatty acids. The metal component of the complexes may be calcium, barium, strontium, magnesium or zinc. The lithium soap of component (2) may be a fatty acid soap. Mixtures of lithium and strontium or lithium and calcium soaps may be employed in component (2). The lubricating oils of components (1) and (2) may be mineral or synthetic. Examples of synthetic oils are hydrocarbons, hydrocarbon polymers, esters (e.g. di-2-ethylhexyl sebacate or di-C8 oxo acelate), complex esters, formals, mercaptals, polyalkylene oxides and silicones. In examples: (A) a grease (1) prepared from mineral lubricating oil, acetic acid, hydrogenated castor oil, hydrogenated fish oil fatty acids, hydrated lime and phenyl alpha naphthylamine is blended with a grease (2) prepared from mineral lubricating oil, tallow fatty acids, hydrated lime and lithium hydroxide monohydrate; and (B) a grease (1) prepared from mineral lubricating oil, acetic acid, caprylic acid, hydrated lime and phenyl alphanaphthylamine is blended with a grease (2) prepared from mineral lubricating oil, methyl 12-hydroxy stearate, lithium hydroxide monohydrate and phenyl alpha naphthylamine.
机译:一种润滑脂组合物,其包含两种组分润滑脂的混合物,组分(1)包括增稠至与金属盐和金属皂或两种或更多种金属盐的配合物的润滑脂稠度的润滑油,和组分(2)包含用锂皂增稠至润滑脂稠度的润滑油,可以选择与其他金属混合使用。组分(1)的配合物可以是(a)由C12-C30羧酸的金属皂和C1-C3羧酸的金属盐制备的皂盐配合物; (b)由C12-C30羧酸的金属皂,C3-C10羧酸的金属盐和乙酸的金属盐制备的皂盐配合物; (c)由C 7 -C 10羧酸的金属盐和C 1 -C 3羧酸的金属盐制备的混合盐配合物。指定的C1-C3酸是甲酸,乙酸,丙酸和乳酸,而提到的C3-C10酸是烷烃一元羧酸和甘油,乳酸,柠檬酸,苯甲酸,羟基苯甲酸,甲苯甲酸,邻苯二甲酸,对苯二甲酸,糠酸和噻吩羧酸。提到的C 7 -C 10酸是烷烃一元羧酸,而C 12 -C 30酸是饱和或不饱和脂肪酸。配合物的金属成分可以是钙,钡,锶,镁或锌。组分(2)的锂皂可以是脂肪酸皂。锂和锶或锂和钙皂的混合物可用于组分(2)中。组分(1)和(2)的润滑油可以是矿物的或合成的。合成油的实例是烃,烃聚合物,酯(例如癸二酸二-2-乙基己酯或乙酰氧基二-C8乙二酸酯),复合酯,缩甲醛,硫醇,聚环氧烷和硅酮。在实例中:(A)将由矿物润滑油,乙酸,氢化蓖麻油,氢化鱼油脂肪酸,熟石灰和苯基α萘胺制得的油脂(1)与由矿物润滑油制得的油脂(2)混合,牛脂脂肪酸,熟石灰和氢氧化锂一水合物; (B)将由矿物润滑油,乙酸,辛酸,熟石灰和苯基α-萘胺制得的油脂(1)与由矿物润滑油,12-羟基硬脂酸甲酯,一水合氢氧化锂和苯基α萘胺。

著录项

  • 公开/公告号US2908645A

    专利类型

  • 公开/公告日1959-10-13

    原文格式PDF

  • 申请/专利权人 ESSO RESEARCH AND ENGINEERING COMPANY;

    申请/专利号US19550504659

  • 发明设计人 MORWAY ARNOLD J.;

    申请日1955-04-28

  • 分类号

  • 国家 US

  • 入库时间 2022-08-23 19:38:48

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