Water-insolubilizing starch-clay paper coatings with a reaction product of dialdehyde starch and a dicyandiamide formaldehyde condensation product

摘要

A paper coating composition having improved wet-rub resistance comprises a mixture of clay and the reaction product of a starch adhesive with a reaction product of a dialdehyde polysaccharide and a dicyandiamideformaldehyde condensation product. The clay may be hydrated aluminium silicate and the dialdehyde polysaccharide may be periodateoxided starches, gums, dextrans, celluloses or inulins. The insolubilized, wet-rub resisting composition may be formed by applying an aqueous dispersion of the reaction product of the dialdehyde polysaccharide and dicyandiamideformaldehyde condensation product (see Division C3) to the surface of a paper-borne starch-clay coating, whereupon the said reaction product further reacts with the starch in the starch-clay coating, to give a coated paper having improved wet-rub resistance (see Division B2).ALSO:A composition for insolubilizing clay-starch adhesive paper coating compositions comprises the reaction product of a dialdehyde polysaccharide and a dicyandiamide-formaldehyde condensation product. An aqueous dispersion of the reaction product may be formed by mixing, at room temperature, an aqueous dispersion of a dialdehyde polysaccharide, e.g. periodateoxidized starches, gums, dextrans, insulins or celluloses, and an aqueous solution of a dicyandiamide-formaldehyd condensation product. The aqueous dispersion preferably has a solid content of 7 to 10% by weight of dialdehyde polysaccharide, and 0.5 to 10% by weight of dicyandiamide-formaldehyde condensation product based on the total volume of the dispersion. The insolubilizing action of the reaction product, a complex resin polymer, is believed to be due to a reaction between aldehyde and methylol groups on the resin and hydroxyl groups on the surface of the starch adhesive coating (see Divisions B2 and C4).ALSO:A coated paper having improved wet-rub resistance comprises a paper substrate provided with a base coating comprising a mixture of clay and a starch adhesive, the base coating having a surface layer comprising a mixture of clay and the reaction product of a starch adhesive with a reaction product of a dialdehyde polysaccharide and a dicyandiamideformaldehyde condensation product. The coated paper may be prepared by applying to paper an aqueous mixture of clay, e.g. hydrated aluminium silicate, and thin boiling starch, drying at room temperature, and then applying to the surface of the coated paper an aqueous dispersion of the reaction product of a dialdehyde polysaccharide, e.g. periodate oxidized starches, inulins, gums, dextrans or celluloses, and the dicyandiamide-formaldehyde condensation product. The above reaction product water-insolubilizes the surface layer of the claystarch coating by reacting, it is believed, with the starch therein (see Divisions C3 and C4).