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Process for the production of nu, nu', nu'-triorgano-substituted borazoles

机译:nu,nu',nu'-三有机取代的硼唑的生产方法

摘要

N,N1,N11 - triorgano-substituted borazoles of the general formula FORM:1003090/C2/1 wherein R represents an alkyl, cycloalkyl, aromatic or substituted aromatic radical, one made by reacting an alkali metal borohydride or an alkali metal aluminium hydride with a carboxylic acid nitrile RCN and a boron trihalide or an addition compound of a boron trihalide with an ether, or by reacting an alkali metal borohydride or an alkali metal aluminium hydride with an addition compound of a boron halide with a carboxylic acid nitrile. The reaction may be effected at a temperature from 0 DEG to 100 DEG C. Suitable starting materials are listed and the preparation of N,N1,N11-triethyl-, tripropyl-and tri - (o - chlorobenzyl) - b ,b 1,b 11 - trihydrogenoborazoles is exemplified. Specification 984,806 is referred to.
机译:N,N1,N11-通式的三有机取代的硼唑,其中R表示烷基,环烷基,芳族或取代的芳族基团,通过使碱金属硼氢化物或碱金属铝反应制得氢化物与羧酸腈RCN和三卤化硼或三卤化硼与醚的加成化合物,或使碱金属硼氢化物或碱金属氢化铝与卤化硼与羧酸腈的加成化合物反应。该反应可以在0℃至100℃的温度下进行。列出了合适的原料,并制备了N,N1,N11-三乙基-,三丙基和三-(邻氯苄基)-b,b 1。 b 11-以三氢硼唑为例。参考规范984806。

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