Method of producing acrylonitrile polymers in the presence of a catalyst comprising octanoyl peroxide or t-butyl peroxypivalate and using as a solvent dimethylsulfoxide or ethylene carbonate

摘要

1,050,140. Solution polymerization of acrylonitrile. TOYO RAYON KABUSHIKI KAISHA. Oct. 13, 1964 [Oct. 21, 1963], No. 41776/64. Heading C3P. Acrylonitrile polymers or copolymers are prepared by polymerizing in solution a monomeric material comprising at least 85 mol. per cent of acrylonitrile using dimethyl sulphoxide or ethylene carbonate as solvent and octanoyl peroxide or t-butyl peroxypivalate as polymerization catalyst. A discoloration inhibitor may be present, e.g. a hydroxylamine salt (e.g. hydrochloride, sulphate, oxalate, phosphate or acetate) preferably together with sulphuric acid. Sodium ethylenediamine tetra-acetate may be included to prevent discoloration by metals. The polymerization may be effected in the presence of a chain transfer agent, e.g. dodecyl mercaptan. The discoloration inhibitors and chain transfer agents may be added during the course of the polymerization. Suitable comonomers for the acrylonitrile include acrylic and methacrylic acid and esters and amides thereof; styrene and substituted styrenes; vinyl chloride and vinylidene chloride; vinyl esters such as the acetate, chloroacetate and benzoate; vinyl-pyridines and their alkyl derivatives; alkenyl aromatic sulphonic acids, vinyl sulphonic acid, allyl sulphonic acid and methallyl sulphonic acid and salts and esters of such acids. Examples illustrate the preparation of polyacrylonitrile and copolymers of acrylonitrile with (a) methyl acrylate and sodium methallyl sulphonate, (b) methyl acrylate and sodium p-styrene sulphonate, (c) vinyl acetate and methacrylic acid and (d) methyl methacrylate and sodium allyl sulphonate. The substantially colourless polymer solutions obtained are spun into fibres.