首页> 外国专利> Mixtures of cis-and trans-3,6-dimethyl-oct-6-en-y n-3-ol and - 3-methyl-6-ethyl-hept -6-en-4-yl-3-ol - for use in perfumery

Mixtures of cis-and trans-3,6-dimethyl-oct-6-en-y n-3-ol and - 3-methyl-6-ethyl-hept -6-en-4-yl-3-ol - for use in perfumery

机译:顺式和反式3,6-二甲基-辛-6-烯基正-3-醇和-3-甲基-6-乙基庚基-6-烯-4-基-3-醇的混合物用于香水

摘要

Mixtures of isomers having the formulae:- (in which R is the same in all the three formulae and denotes H or a 2-8C acyl). Pref. mixts. consist of (I) and (III) isomers; trans-3,6-dimethyl-oct-6-en-4-in-3-ol is claimed as novel. These cpds. have lavender like scent. They are produced by reacting a mixt. of corresp. enins with MEK in presence of an alkali hydroxide or alcoholate; hydrolysing the products and opt. reacting with a monocarboxylic acid anhydride or chloride (if R is acyl).
机译:具有下式的异构体的混合物:(其中三个式中R均相同,表示H或2-8C酰基)。首选混音。由(I)和(III)异构体组成;反式3,6-二甲基-辛基-6-en-4-in-3-醇被认为是新颖的。这些cpds。像薰衣草一样散发香味。它们是通过混合反应产生的。的Corresp。在碱金属氢氧化物或醇盐存在下与MEK结合;水解产品并选择。与一元羧酸酐或氯化物(如果R为酰基)反应。

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