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compositions organopolisilossaniche that vulcanizzano already the temperature environment for elasto tem meri belonging to various media

机译:组成vulcanizzano的organopolisilossaniche的温度环境已经属于属于各种介质的弹力蛋白

摘要

The properties of organosilicon compositions based on alpha - omega -dihydroxy diorganopolysiloxanes, methyl polysiloxanes, fillers, amino organosilicon corss linking agents and optionally alkyl silicates or polysilicates, which are vulcanisable at ambient temperature or above, are improved by using a methylpolysiloxane in which the ratio of the R(CH3)2SiO0.5 units (R=C1-C3 alkyl or vinyl) to SiO2 units is 0.4:1 to 1.2:1 and which contains 0.5 - 3.5% by weight OH groups bonded to Si and by using an amino organosilicon compound which is an aminoorganosilane of the general formula (i) (R''O)3- pR'pSi[(CH2)nO]m (CH2)tNHQ in which R' represents an alkyl group with 1 to 4 carbon atoms, a vinyl group or a phenyl group, R'' represents a methyl, ethyl or methoxyethyl radical, Q represents a hydrogen atom or the radical -(CH2)2NH2, p and m represent 0 or 1, n represents 1, 2, 3 or 4, and t represents 2 or 3, or an aminoorganopolysiloxane produced by reacting the aminoorganosilane (i) above, in which p is 0, with a hydroxylic methylpolysiloxane polymer (ii) containing at least 2% by weight of hydroxyl groups bonded to the silicon atoms, of viscosity 1 cPo at 25 DEG C to 1,000 cPo at 25 DEG C, of the average general formula (CH3)a(HO)bSiO(4-a-b)/2 in which a represents any number from 1.6 to 2.3 and b represents any number ranging from 0.1 to 1; the amounts of aminoorganosilane (i) and hydroxylic methylpolysiloxane polymer (ii) being such that there are 0.4 to 1.2 mols of (i) per gram-(hydroxyl group) (that is to say 17 g) of (ii). The new compositions have improved fluidity characteristics and pot life, and adhere easily to most surfaces without using a primer and can be used particularly to protect electronic connections.
机译:通过使用甲基聚硅氧烷来改善基于α-ω-二羟基二有机聚硅氧烷,甲基聚硅氧烷,填料,氨基有机硅皮质键合剂和任选的烷基硅酸盐或聚硅酸盐的有机硅组合物的性质,所述有机硅组合物在环境温度或更高温度下可硫化。 R(CH 3)2 SiO 0.5单元(R = C 1 -C 3烷基或乙烯基)与SiO 2单元的比为0.4∶1至1.2∶1,并且含有0.5-3.5重量%的与Si结合并通过使用氨基键合的OH基。 (R)O)3-pR'pSi [(CH 2)n O] m(CH 2)tNHQ的通式(i)的氨基有机硅烷的有机硅化合物,其中R'代表具有1-4个碳原子的烷基, R''表示甲基,乙基或甲氧基乙基,Q表示氢原子或-(CH2)2NH2基团,p和m表示0或1,n表示1、2、3或在图4中,t表示2或3,或通过使上述氨基有机硅烷(i)反应而生成的氨基有机聚硅氧烷,其中p为0,其中羟基甲基聚硅氧烷聚合物(ii)含有至少2%(重量)键合到硅原子上的羟基,其平均通式的粘度在25℃为1 cPo,在25℃为1,000 cPo (CH3)a(HO)bSiO(4 -a -b)/ 2,其中a表示1.6至2.3之间的任何数字,b表示0.1至1范围内的任何数字;氨基有机硅烷(i)和羟基甲基聚硅氧烷聚合物(ii)的量应使得每克(ii)-(羟基)(即17g)有0.4至1.2摩尔(i)。新的组合物具有改善的流动性和适用期,并且无需使用底漆即可轻松粘附于大多数表面,可特别用于保护电子连接。

著录项

  • 公开/公告号IT1012272B

    专利类型

  • 公开/公告日1977-03-10

    原文格式PDF

  • 申请/专利权人 RHONE POULENC SA;

    申请/专利号IT19740022590

  • 发明设计人

    申请日1974-05-10

  • 分类号C08G;

  • 国家 IT

  • 入库时间 2022-08-23 00:38:13

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