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Crystalline zeolite catalysts for hydrocarbon CONVERSION - with improved stability, selectivity and activity

机译:用于烃类转化的结晶沸石催化剂-具有改善的稳定性,选择性和活性

摘要

Crystalline alumino-silicate zeolites with SiO2/Al2O3 molar ratio of 4.6-5.4, face-centered cubic structure with cell size 24.45-24.55 angstrom Na2O/Al2O3 molar ratio of 0.25 max., pref. below 0.038, adsorption capacity for oxygen in the dehydrated state of at least 26 wt. % at 100 torr oxygen pressure at -183 degrees C, ion exchange capacity 0.15-0.35 and the X-ray powder diffraction diagram of Zeolite Y with the exception that d-separation for the Miller Index 331 line is at least as intensive as the line with Miller Index 533. Used for conversion of hydrocarbons e.g. cracking, hydrocracking, reforming, polymerise., isomerisn., alkylation and hydro-alkylation. The catalysts have high stability, selectivity and activity with high resistance to crystal degradation by heat and steam.
机译:SiO2 / Al2O3摩尔比为4.6-5.4,面心立方结构,晶胞尺寸为24.45-24.55埃的Na2O / Al2O3摩尔比最大为0.25的结晶铝硅酸盐沸石。低于0.038,在脱水状态下对氧气的吸附能力至少为26 wt。%。在100托氧气压力下,-183℃时的%,离子交换容量0.15-0.35,以及沸石Y的X射线粉末衍射图,但米勒指数331线的d分离强度至少与该线相同米勒指数533。用于烃的转化,例如裂化,加氢裂化,重整,聚合,异构化,烷基化和加氢烷基化。该催化剂具有高的稳定性,选择性和活性,并且具有高的抗热和蒸汽降解晶体的能力。

著录项

  • 公开/公告号DE000002523315C2

    专利类型

  • 公开/公告日1977-02-10

    原文格式PDF

  • 申请/专利权人

    申请/专利号DE2523315A

  • 发明设计人

    申请日1975-05-27

  • 分类号C01B33/26;

  • 国家 DE

  • 入库时间 2022-08-23 00:09:28

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