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ALPHA,BETA-UNSATURATED SCHIFF-BASE CHAIN EXTENSION REACTIONS FOR HIGH TEMPERATURE POLYMERS

机译:高温聚合物的Alpha,BETA不饱和席夫基链扩展反应

摘要

1487258 Polyimides CIBA-GEIGY AG 24 Dec 1974 [26 Dec 1973] 55834/74 Heading C3R A curable composition comprises (a) a compound of one of the following average formulµ and (b) 1 to 10 mole equivalents of a bis-dienophile of one of the formulµ In the formulµ at least 5% of the Z groups are -N=CR 1 -CR 2 =CR 3 R 4 and the remainder NH 2 ; n is 0 or a number up to 20; R 1 to R 4 are H or monovalent organic radicals; R 5 and R, are C 2-30 divalent organic radicals; R 6 is a tetravalent organic radical; m is 1 to 20; and D is an olefinic radical wherein R 16 is H, CH 3 , Br or Cl; R 17 is H, Br or Cl; YSP1/SP to YSP6/SP are H, Br, Cl, NO 2 , C 6 H 5 or C 1-6 alkyl; and X is CO, O, S, Cl- or Br-substituted CH 2 , C 1-6 alkylidene or benzylidene. The compositions are processable by conventional plastics processing techniques at relatively low temperatures and are useful as moulding powders, laminating resin, adhesives, coatings and monofilament windings. Reference is made to Specification 1,457,270. Reference has been directed by the Comptroller to Specification 1,190,718.
机译:1487258聚酰亚胺CIBA-GEIGY AG 1974年12月24日[1973年12月26日] 55834/74标题C3R一种可固化的组合物,包含(a)以下平均分子量之一的化合物和(b)1至10摩尔当量的双-亲二烯体式中的一个在式中,Z基团的至少5%为-N = CR 1 -CR 2 = CR 3 R 4,其余为NH 2。 n为0或不超过20的数字; R 1〜R 4为H或一价有机基团。 R 5和R 1是C 2-30二价有机基团; R 6是四价有机基团; m为1至20; D为烯基,其中R 16为H,CH 3,Br或Cl; R 17为H,Br或Cl; Y 1 至Y 6 为H,Br,Cl,NO 2,C 6 H 5或C 1-6烷基; X是CO,O,S,Cl或Br取代的CH 2,C 1-6亚烷基或亚苄基。该组合物可通过常规的塑料加工技术在较低的温度下加工,并且可用作模压粉,层压树脂,粘合剂,涂料和单丝缠绕物。参考规范1,457,270。主计长已将规范1,190,718引为参考。

著录项

  • 公开/公告号GB1487258A

    专利类型

  • 公开/公告日1977-09-28

    原文格式PDF

  • 申请/专利权人 CIBA GEIGY AG;

    申请/专利号GB19740055834

  • 发明设计人

    申请日1974-12-24

  • 分类号C08G73/12;

  • 国家 GB

  • 入库时间 2022-08-22 23:39:02

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