METHOD AND APPARATUS FOR CARRYING OUT GAS PHASE REACTIONS IN THE PRESENCE OF A SOLID PARTICULATE CATALYST AND FOR CONTINUOUSLY REGENERATING THE CATALYST SO THAT THE REGENERATION AND REACTION STEPS ARE ISOLATED FROM EACH OTHER

摘要

1487336 Catalyst regeneration in I.C. exhaust treatment A M SOLDATE 28 Nov 1974 [30 Nov 1973] 51525/74 Heading B1F An apparatus for carrying out gas phase reactions in the presence of fluidised particulate catalvst, e.g. the treatment of I.C. engine exhaust gases, and for simultaneously withdrawing catalyst, regenerating it and returning it to the reaction zone comprises a closed circuit containing an elongated reaction chamber 41 having a spaced apart inlet 41b and outlet 41a; an elongated regeneration chamber 46 having a spaced apart inlet and outlet; a tubular feed conduit 48 connecting the reactor outlet and regenerator inlet; a tubular return conduit 50 connecting the regenerator outlet and reactor inlet; inlet and outlet means 54, 58 for passing a stream of reactant gas through the reaction chamber in countercurrent flow to fluidised catalyst; means for regenerating spent catalyst in the regeneration chamber; and means for vibrating the closed circuit to force circulation of the catalyst in a fluidised manner, preferably horizontally, around the closed circuit in such a manner that conduits 48 and 50 are maintained in a filled condition to prevent interaction between reactions taking place in the reaction zone and the regeneration zone. The apparatus may be vibrated by suspending it by three coil springs 214 from fixed brackets 44 and engaging it with a rotating shaft 228 carrying counterweights 218 and 220 at its upper and lower ends. By varying the radial angle between the two weights, the speed of rotation and relative mass of the counterweights the direction of flow form of motion applied to the catalyst particles may be controlled. The shaft 228 is connected to the drive means 224 by a flexible connection to avoid transfer of vibration to the drive means. The catalyst may be regenerated by counterflow contact with regeneration gas, e.g. air to burn off carbon, introduced through lines 46a and 46b. The regenerator may contain an electrically-heated tubular furnace 60 to heat the catalyst. A pair of separate catalyst regeneration chambers may be used, the catalyst being heated in one regeneration circuit and cooled in the next. One method of regeneration involves impingement of spent catalyst particles with the heated wall of a chamber formed of the same material as the catalyst with resultant deposition of a fresh surface layer on the catalyst particles. The gas outlet 58 from the reaction chamber may include a cyclone 64 to separate any catalyst particles thus carried out of the chamber and a return pipe 71 for separated catalyst.