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Process for producing terephthalic acid by catalytic liquid phase oxidation of para-xylene

机译:对二甲苯催化液相氧化生产对苯二甲酸的方法

摘要

A process for producing terephthalic acid by the catalytic liquid phase oxidation of para-xylene with either molecular oxygen or a gas containing molecular oxygen and recovering terephthalic acid from the liquid phase oxidation reaction product; characterized in that (1) the recovery of terephthalic acid is performed at a temperature (T.sub.2) which satisfies the following equation ##EQU1## wherein (T.sub.1) is the temperature of the above liquid phase oxidation, and (2) a part or whole of the catalyst-containing mother liquor remaining after the recovery of terephthalic acid is recycled to the catalytic liquid phase oxidation while maintaining it at a temperature (T.sub.3) which satisfies the following equation ##EQU2##wherein (T.sub.2) is the temperature employed in the recovery of terephthalic acid.
机译:一种通过对二甲苯用分子氧或含分子氧的气体催化液相氧化生产对苯二甲酸并从液相氧化反应产物中回收对苯二甲酸的方法。其特征在于(1)对苯二甲酸的回收在满足以下方程式## EQU1 ##的温度(T.sub.2)下进行,其中(T.sub.1)是上述液相氧化的温度。 (2)将回收对苯二甲酸后剩余的部分或全部的含催化剂母液循环到催化液相氧化,同时将其保持在满足下式#的温度(T.sub.3)。 #EQU2 ##其中,(T.sub.2)是对苯二甲酸回收中使用的温度。

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