production of chlorine by electrolysis of halides of metals in an electrolytic cell having alacalini catalytic electrodes connected to the surface of a solid electrolyte membrane polimerico.

摘要

A halogen, such as chlorine, is generated by electrolysis of an aqueous solution of an alkali metal halide such as sodium chloride, in a cell having anolyte and catholyte chambers separated by a solid polymer electrolyte in the form of a stable, selectively cation permeable, ion exchange membrane 13. One or more catalytic electrodes 14, 29 including at least one thermally stabilized, reduced oxide of a platinum group metal, optionally with oxide of a transition or valve metal and graphite are bonded to the surface of the membrane. An aqueous brine solution is brought into contact with the anode and water or an aqueous NaOH solution is brought into contact with the cathode. The brine is electrolyzed to produce chlorine at the anode and hydrogen and caustic at the cathode. The cell membrane preferably has an anion rejecting cathode side barrier layer which rejects hydroxyl ions to block back migration of caustic to the anode thereby enhancing the cathode current efficiency of the cell and of the process. The catalytic anode is preferably gas permeable, comprising particles of the thermally stabilized, reduced oxides bonded together by a fluorocarbon polymer. IMAGE