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PHOTOSENSITIZED REACTIONS UTILIZING POLYMER-BOUND PHOTOSENSITIZING CATALYSTS

机译:利用聚合物键合光敏催化剂进行光敏反应

摘要

ABSTRACT OF THE DISCLOSUREThe present invention provides a method for the hetero-geneously catalyzed singlet oxygen photooxidation of a photo-oxidizable organic compound capable of adding oxygen by reactionwith singlet oxygen, which comprises simultaneously subjectingsaid photooxidizable organic compound in an inert solvent tolight irradiation and contact with molecular oxygen and a polymer-bound photosensitizing catalyst insoluble in the reaction medium,thereby introducing oxygen into the molecule of said photo-oxidizable organic compound by reaction with singlet oxygengenerated from said molecular oxygen by energy transfer from saidlight irradiation and said polymer-bound photosensitizing catalyst,said polymer-bound photosensitizing catalyst comprising thenucleophilic displacement reaction product of (A) a polymericmaterial having attached thereto an available leaving group whichis capable of being displaced in a nucleophilic displacementreaction with a nucleophilic reagent and (B) a photosensitizerdye containing in its molecule a nucliophilic which is capable ofdisplacing said leaving group attached to said polymeric materialin a nucleophilic displacement reaction.
机译:披露摘要本发明提供了一种用于的光催化的单线态氧光氧化能够通过反应加氧的可氧化有机化合物单线态氧,其中包括同时进行在惰性溶剂中将所述可光氧化的有机化合物光照射并与分子氧和聚合物接触-不溶于反应介质的结合光敏催化剂从而将氧气引入所述光子分子中与单线态氧反应可氧化的有机化合物由分子氧通过能量转移产生光照射和所述聚合物结合的光敏催化剂,所述聚合物结合的光敏催化剂包括:(A)聚合物的亲核取代反应产物具有可连接的离去基团的材料能够被亲核取代与亲核试剂和(B)光敏剂反应分子中含有亲核性的染料取代附着在所述聚合物材料上的所述离去基团在亲核取代反应中。

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