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This is intended to reduce the formation of dimers during the production of compounds lower by hydrolysis of a corresponding carboxylic ester

机译:旨在减少在相应的羧酸酯水解过程中生成较低化合物的过程中二聚体的形成

摘要

Brief description of the drawings for the production of compounds polyhydroxyl 2 has 6c from their carboxylates lower. / p & & p & the initial mixture containing the carboxylate inferior, is hydrolyzed with water at 6 in the presence of a catalyst, which gives, at 18, a product, containing the composed polyhydroxyl, the carboxylic acid, water and of the fragments of catalyst, and which is distilled at 20 in order to give a first product of the head 22 containing the water and a first product of the shank 35 containing the composed polyhydroxyl and the carboxylic acid; this product is distilled, 35, 36, to give a second product of the head 38 containing the carboxylic acid, and a second end 46 containing the product comprises polyhydroxyl and which is treated, 80, in order to extract the composed polyhydroxyl. / p & & p & application: obtaining ethylene - or propylene - glycol practically free of products in - dimers.
机译:附图说明用于制备化合物的多羟基2具有从它们的羧酸盐较低的6c。 & &在催化剂存在下,将含劣质羧酸盐的初始混合物在6℃下用水水解,在18℃时得到含有所组成的多羟基,羧酸,水和催化剂片段的产物,在20℃下蒸馏以得到含有水的头部22的第一产物和含有所组成的多羟基和羧酸的小腿35的第一产物;在35、36蒸馏该产物,得到含有羧酸的头38的第二产物,并且含有该产物的第二末端46包含多羟基,并对其进行处理80,以提取所组成的多羟基。 & &应用:获得几乎不含二聚体产物的乙烯或丙二醇。

著录项

  • 公开/公告号FR2408568A1

    专利类型

  • 公开/公告日1979-06-08

    原文格式PDF

  • 申请/专利号FR19780032007

  • 发明设计人

    申请日1978-11-13

  • 分类号C07C31/18;

  • 国家 FR

  • 入库时间 2022-08-22 19:32:22

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