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High molecular weight high unsaturation C.sub.4 -C.sub.10 isoolefin conjugated diolefin copolymers and multipolymers containing methylcyclopentadiene

机译:高分子量高不饱和C.sub.C.C.sub.10异烯烃共轭二烯烃共聚物和含有甲基环戊二烯的共聚物

摘要

Substantially gel-free high unsaturation copolymers of isobutylene and methylcyclopentadiene and high unsaturation terpolymers of isobutylene cyclopentadiene and methylcyclopentadiene and terpolymers of isobutylene, isoprene and methylcyclopentadiene having a number average molecular weight of at least about 120,000 and a mole percent of unsaturation of at least 5% and the process for preparing said polymers which comprises carrying out the polymerization in a homogeneous phase, introducing to the system either an aluminum halide in a soluble form or a hydrocarbylaluminum dihalide and carrying the reaction out at a temperature of less than about -100° C.
机译:异丁烯和甲基环戊二烯的基本上无凝胶的高不饱和共聚物和异丁烯环戊二烯和甲基环戊二烯的高不饱和三元共聚物以及数均分子量为至少约120,000且不饱和摩尔百分比至少为5%的异丁烯,异戊二烯和甲基环戊二烯的三元共聚物以及制备所述聚合物的方法,该方法包括在均相中进行聚合,将可溶形式的卤化铝或烃基二卤化铝引入系统中,并在小于约-100℃的温度下进行反应。

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