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A process for selectively removing minor amounts of beta-chloroacroleins and 5,6-epoxyhexene-1 from epichlorohydrin

机译:从表氯醇中选择性除去少量β-氯丙烯醛和5,6-环氧己烯-1的方法

摘要

The invention relates to a process for selectively removing minor amounts of beta-chloroacroleins and 5,6-epoxyhexene-1 from a mixture made up predominantly of epichlorohydrin, characterized by treating said mixture with hydrogen at a temperature of between 20°C and 150°C in the presence of a catalyst comprising rhodium, platinum or palladium deposited on a non-acidic, refractory support, in an amount of from 0.05 to 10% by weight on the total catalyst and to epichlorohydrin whenever prepared by means of this process.
机译:本发明涉及从主要由表氯醇组成的混合物中选择性除去少量β-氯丙烯醛和5,6-环氧己烯-1的方法,其特征在于在20℃至150℃之间用氢气处理所述混合物。在通过沉积在非酸性耐火载体上的包含铑,铂或钯的催化剂存在的情况下,无论何时通过该方法制备,C的量为总催化剂和表氯醇的0.05-10重量%。

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