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Hydrolytically stable hydraulic fluids - based on amino:silane(s) which are soluble in glycol- and silicone-based hydraulic fluids

机译:水解稳定的液压油-基于氨基:硅烷,可溶于基于乙二醇和硅酮的液压油

摘要

A hydraulic fluid contains 1 or more aminosilane of formula R(4-n)Si(NR1R2)n (I) (where R is 1-12C alkyl or alkoxy, 2-12C alkenyl, aryl, arylalkyl, 3-10C cycloalkyl, or a gp. R'(OCHR3CHR4)x or H(OCHR3CHR4)x; where R' is 1-4C alkyl, R3 and R4 are H or 1-3C alkyl and x is 1-5; R1 is H or R, omitting the alkenyl gp., R2 is R, omitting the alkenyl gp; n is 1-3). A pref. compsn. for the hydraulic fluid has 30-70 wt.% (I), 30-70 wt.% of 1 or more oxyalkyleneglycolmono- or dialkyl ethers, and 0-40 wt.% of a mixt. of 1 or more boric esters with an appropriate glycol or deriv. The aminosilanes are sol. in glycol-based as well as in silicone-based hydraulic fluids. Their hydrolytic stability is much higher than that of e.g. silicate esters currently used, and pptn. of hydrolysis prods. can be further suppressed by addns. of inhibitors and/or solvents.
机译:液压流体包含一种或多种式R(4-n)Si(NR1R2)n(I)的氨基硅烷(其中R为1-12C烷基或烷氧基,2-12C烯基,芳基,芳基烷基,3-10C环烷基或g.R'(OCHR3CHR4)x或H(OCHR3CHR4)x;其中R'为1-4C烷基,R3和R4为H或1-3C烷基,x为1-5; R1为H或R,省略了烯基gp。,R2为R,省略烯基gp; n为1-3)。偏爱compsn。用于液压流体的油具有30-70重量%(I),30-70重量%的一种或多种氧化烯二醇单-或二烷基醚和0-40重量%的混合物。一种或多种硼酸酯与适当的乙二醇或衍生物的混合物。氨基硅烷是溶胶。在乙二醇基和硅基液压油中使用。它们的水解稳定性远高于例如目前使用的硅酸酯和pptn。水解产物。可以被addns进一步抑制。抑制剂和/或溶剂。

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