首页> 外国专利> A method for the production of at least 1 of the metals palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold, copper, cadmium, nickel, cobalt, iron and rhenium, and, if applicable. At least 1 of the metals zinc, mercury, germanium, tin, antimony and lead to metal catalysts containing catalyst brackets

A method for the production of at least 1 of the metals palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold, copper, cadmium, nickel, cobalt, iron and rhenium, and, if applicable. At least 1 of the metals zinc, mercury, germanium, tin, antimony and lead to metal catalysts containing catalyst brackets

机译:一种生产至少一种金属钯,铑,钌,铂,铱,,银,金,铜,镉,镍,钴,铁和rh(如果适用)的方法。锌,汞,锗,锡,锑和铅中的至少一种金属含有催化剂支架的金属催化剂

摘要

The invention relates to a new process for the preparation of a supported metal catalyst containing at least one metal belonging to Group A and optionally at least one metal belonging to Group B, wherein Group A encompasses the metals palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold and cadmium and Group B encompasses the metals zinc, mercury, germanium, tin, antimony and lead. According to the invention, the metal(s) is (are) applied onto the support in the presence of at least one compound of the general formula (I), IMAGE (I) wherein R1, R2, R3 and R4 each stands for a straight-chained or branched C1-20 alkyl group, a C1-4 hydroxyalkyl group or a phenyl-(C1-4 alkyl) group optionally having additional substituents, preferably C1-4 alkyl groups, on the phenyl ring, and X is hydroxy group or the residue of an organic or mineral acid. According to the invention, highly active catalysts can be prepared by an easy and economical process.
机译:本发明涉及一种制备负载型金属催化剂的新方法,该催化剂包含至少一种属于A族的金属和任选地至少一种属于B族的金属,其中A族包括钯,铑,钌,铂,铱金属,,银,金和镉,而B组则包括锌,汞,锗,锡,锑和铅。根据本发明,在至少一种通式(I),(I)的化合物的存在下将一种或多种金属施加到载体上,其中R1,R2,R3和R4分别为对于直链或支链C 1-20烷基,C 1-4羟烷基或苯基-(C 1-4烷基)基团在苯环上任选具有其他取代基,优选C 1-4烷基,且X为羟基或有机或无机酸的残基。根据本发明,可以通过简单且经济的方法制备高活性催化剂。

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