首页> 外国专利> kvaternaera ammoniumfoereningar innehaollande ytaktiva anjoner, dessas polymerer, polymeriserbara kompositioner innehaollande states foerfaranden foer framstaellning av monomererna och polymererna och artiklar innehaollande denna polymer

kvaternaera ammoniumfoereningar innehaollande ytaktiva anjoner, dessas polymerer, polymeriserbara kompositioner innehaollande states foerfaranden foer framstaellning av monomererna och polymererna och artiklar innehaollande denna polymer

机译:含有表面活性剂阴离子的季铵化合物,它们的聚合物,含有用于制备单体和聚合物的状态方法的可聚合组合物以及含有该聚合物的制品

摘要

The quaternary ammonium monomers of this invention have the formula CHEM wherein R is an ethylenically unsaturated organic group R1 is a linear C1 to C4 alkyl group, optionally hydroxy substituted X is chlorine, bromine or iodine, and Y(-) is a surfactant anion. The epoxides derivable from the halohydrin of Formula (I) are other monomers of this invention. The monomers are soluble in common organic solvents and comonomers. The invention is also directed to addition polymers of these monomers and to methods or producing both the monomers and the colymers. The halohydrin monomers and the polymers are stable at acid pH values although capable of reacting with materials reactive with the hydroxyl and/or halide groups. Upon heating, they are self-reactive and can become cross-linked. At alkaline pH values they become self-reactive; the polymers crosslink slowly even at room temperature, with a crosslinking rate increasing rapidly with temperature. The monomers are particularly efficiently incorporated into copolymers. Polymers containing the novel monomers are useful as coating, binding or impregnating compositions.
机译:本发明的季铵单体具有式,其中R是烯键式不饱和有机基团R 1是直链的C 1 -C 4烷基,任选被羟基取代的X是氯,溴或碘,并且Y <(- )是表面活性剂阴离子。衍生自式(I)的卤代醇的环氧化物是本发明的其他单体。单体可溶于常见的有机溶剂和共聚单体。本发明还涉及这些单体的加成聚合物以及方法或生产单体和共聚体两者。卤代醇单体和聚合物在酸性pH值下是稳定的,尽管能够与对羟基和/或卤化物基团具有反应性的材料反应。加热时,它们是自反应的,可以交联。在碱性pH值下,它们会发生自我反应。聚合物甚至在室温下也缓慢交联,交联速率随温度迅速增加。单体特别有效地掺入共聚物中。含有新型单体的聚合物可用作涂料,粘合或浸渍组合物。

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