4-Nitro-4'-amino-diphenylamine-2-sulfonic acid, 2-nitro-4'-amino-diphenylamine-4-sulfonic acid and their sodium salts are obtained in good yield and high purity by condensing 6- or 4-chloro-3-nitro-benzene sulfonic acid and 1,4-phenylene diamine in a saturated aqueous sodium chloride solution. The products and their desulfonation derivatives are dye precursors.
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