Compositions which are stable in the absence of oxygen are formed by mixing the following substantially in the absence of oxygen: (A) 100 parts by weight of at least one mercapto-functional organosilicon-organic copolymer or mixtures of at least two different types of components selected from the following three types: the above copolymers, mercapto-functional organic compounds free of silicon atoms and mercapto-functional organosilicon compounds wherein all three types contain an average of at least two mercapto groups per molecule (B) 0-200 parts by weight of at least one filler (C) a catalytic amount, preferably from 0.1 to 6 parts by weight, of an iron carbonyl catalyst selected from the group consisting of Fe(CO)5, Fe2(CO)9, Fe3(CO)12, dicyclopentadienyldiiron tetracarbonyl, butadieneiron tricarbonyl and cyclohexadieneiron tricarbonyl and (D) 0.1-6 parts by weight of an acid, such as 2-ethylhexanoic acid, which meets a particular set of criteria. The compositions polymerize or cure to form higher molecular weight products at room temperature upon exposure to oxygen. These compositions are especially useful as coatings such as for paper or as electrical insulation because they possess a rapid rate of surface cure. Elastomeric sealant compositions can be prepared which rapidly become tack-free at the surface and are less prone to surface contamination by foreign matter such as dust during cure.
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