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Method for reducing the content of heavy metals, including Cadmium compounds in the raw phosphate.

机译:减少粗磷酸盐中重金属含量的方法,包括镉化合物。

摘要

Method for reducing the content of heavy metals, including Cadmium compounds in the raw phosphate.Gross Mixed phosphate, nitric acid to 30 - 70 and CALCIUM NITRATE solution with a concentration of 10 - 50 weight and adjusts the PH of the mixture to 0.2 - 3 by using an Acid Solution, such as nitric acid, Phosphoric Acid, hydrochloric acid or mixtures thereof, and the proportion of raw phosphate to li Liquids added 0.3 - 3: 1.It separates the phosphate Gross, for example by Filtration, and then performs a Neutralization of Sodium Hydroxide, for example, the solution containing Heavy Metals, these Metals are precipitated as sulphides adding Hydrogen sulfide, proceeded a Body of a Neutralization, or extracted Heavy Metals with an agent, extractionAs a ditiofosfinico acid. In all these cases the CALCIUM NITRATE is returned at the beginning of the process.
机译:减少粗磷酸盐中重金属含量的方法,包括粗磷酸盐,硝酸和30-70的硝酸钙溶液,以及浓度为10-50重量的硝酸钙溶液,并将混合物的PH调节为0.2-3通过使用硝酸,磷酸,盐酸或其混合物之类的酸性溶液,并以0.3:3:3:1的比例添加液体中的粗磷酸盐比例,例如通过过滤分离出总磷酸盐,然后进行例如,用氢氧化钠中和,例如,含有重金属的溶液,将这些金属以硫化物的形式加入硫化氢沉淀,进行中和,或用试剂萃取重金属,以二氟膦酸的形式萃取。在所有这些情况下,都会在过程开始时返回硝酸钙。

著录项

  • 公开/公告号ES8400989A1

    专利类型

  • 公开/公告日1984-02-16

    原文格式PDF

  • 申请/专利号ES19830519691

  • 发明设计人

    申请日1983-02-10

  • 分类号C01B25/32;

  • 国家 ES

  • 入库时间 2022-08-22 09:06:24

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