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Method for the production of humic and fulvic acids and intermediate products from peat, peat soils and humic organic materials

机译:由泥炭,泥炭土和腐殖质有机材料生产腐殖酸和黄腐酸及中间产物的方法

摘要

1. Process for the production of humic and fulvic acids and of by products from peat, peaty soils, naturally or artificially humified organic materials, for agricultural, chemical, pharmaceutical, medical and industrial use and for other developments, consisting of : a sorting of the materials to be processed, separating the selected useful material from that devoid of interest ; a breaking up and a sifting of the selected useful material ; the addition of an alkaline solution for the purpose of forming a suspension for the extraction of the humic and fulvic substances contained in this suspension ; the introduction of the suspension into a reactor, keeping it under agitation for a time and at a temperature suitable for the purpose of optimal extraction of the humic and fulvic acids present ; characterised : a) by the subdivision of the useful matter broken up and sifted in accordance with known technology (1) (2) in two cycles : the first (3, 4, 5, 6, 6', 6", 7, 8, 9, 10, 11, 12, 13, 14, 15) for the purpose of the preparation of humic and fulvic acids and of fertilisers or materials for the preparation of fertilisers, the second (19, 20', 20", 21, 4, 5, 16) to obtain a mud rich in humic and fulvic acids and devoid of minerals (iron, aluminium etc.) ; b) for the first cycle, by the addition to the broken up and sifted material in accordance with already known technology (1) (2) of water (3) and of alkali, in a reactor (4) to form a suspension and by the introduction of the suspension into a setting tank (6, 6', 6") leaving it for sedimentation i. e. for the separation of the settled product into various layers, in particular for the separation of a dense lower layer (6"), an intermediate layer (6) ready for use and a fine upper layer (6') ; c) by the separation of the fine upper layer (6') referred to in paragraph b) containing the salts of the humic and fulvic acids, with further successive sedimentations until clarity is obtained, separating for its subsequent treatment the liquid phase from the solid phase which is added to the intermediate layer (6) referred to in paragraph b) ; d) by the treatment of the clear solution (6') referred to in paragraph b) in a column (8) with cation exchange resin enabling the anions to form the desired humic and fulvic acids ; e) by the regeneration (9) of the cation exchange resin, obtaining a by-product usable as a fertiliser ; f) by the separation (10) of the fraction of the middle layer (6) referred to in paragraph b), using it as intermediary matter for the production of solid and liquid fertilisers (13) ; g) by the formation of a fertilising "panel" or an aggregate from the dense lower layer (6") referred to in paragraph b) by drying it and mixing it with other fertilisers for agricultural use (12) ; h) for the second cycle referred to in paragraph a) a disaggregation (19) (crushing) in the presence of water is carried out, then a settling (20', 20"), the lower mineral portion (panel 20") separating from the upper organic portion (20') subjected to a filtration (21) for its introduction into a reactor (4) with return to the first cycle and extraction (5) of a mud rich in humic and fulvic acids (16) devoid of mineral substances for the production of fertiliser complexes or of mixtures.
机译:1.用于农业,化学,制药,医疗和工业用途以及其他发展的由泥炭,豆腐土,天然或人工腐殖的有机材料生产腐殖酸和黄腐酸及其副产品的方法,包括:将要处理的材料,从没有兴趣的材料中分离出有用的材料;选定的有用材料的分解和筛分;为了形成悬浮液而提取碱性溶液,以提取该悬浮液中含有的腐殖质和腐殖质;将悬浮液引入反应器中,使其保持搅拌一定时间和温度,以最佳地提取存在的腐殖酸和黄腐酸;其特征在于:a)通过将有用物质按照已知技术(1)(2)进行细分和筛选,分为两个循环:第一个(3,4,5,6,6',6“,7,8 ,9、10、11、12、13、14、15)用于制备腐殖酸和黄腐酸以及肥料或肥料的材料,第二种(19、20',20“,21, 4,5,16)以获得富含腐殖酸和黄腐酸且不含矿物质(铁,铝等)的泥浆; b)对于第一循环,通过在反应器(4)中根据已知技术(1)(2)将水(3)和碱加入到破碎和筛分的材料中,形成悬浮液,并且将悬浮液引入到沉淀池(6、6',6”)中以使其沉降,即用于将沉降产物分离成不同的层,特别是用于分离致密的下层(6”),准备使用的中间层(6)和精细的上层(6'); c)通过分离包含腐殖酸和黄腐酸的盐的b)段中提到的精细上层(6'),进一步连续沉淀直至获得澄清,将液相与固体分离用于其后续处理相被添加到段落b)中提到的中间层(6)中; d)通过用阳离子交换树脂处理在列(8)中的b)段中提到的澄清溶液(6'),使阴离子能够形成所需的腐殖酸和富里酸。 e)通过阳离子交换树脂的再生(9),获得可用作肥料的副产物; f)通过分离(10)段b)中提到的中间层(6)的一部分,将其用作生产固体和液体肥料(13)的中间物质; g)通过将段b)中提到的致密的下层(6”)中的肥料“面板”或骨料干燥并与其他农业用肥料(12)混合而形成;在a)段所述的循环中,在有水的情况下进行分解(19)(粉碎),然后进行沉降(20',20“),下部矿物部分(面板20”)与上部有机部分分离过滤器(20')经过过滤(21)以引入反应器(4)中,并返回到第一循环并提取(5)富含腐殖酸和富里酸的泥浆(16),该泥土不含矿物物质用于生产肥料配合物或混合物。

著录项

  • 公开/公告号EP0117223A1

    专利类型

  • 公开/公告日1984-08-29

    原文格式PDF

  • 申请/专利权人 LABORATORI FERRINI S.A.;

    申请/专利号EP19840810019

  • 发明设计人 SAVOINI GUIDO;

    申请日1984-01-11

  • 分类号C05F11/02;A61K35/10;

  • 国家 EP

  • 入库时间 2022-08-22 08:57:25

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