首页> 外国专利> AGENT WITH INSECTICIDAL AND ACARICIDAL EFFECT COMPRISING 3-ALKEN-1-YL-2,2-DIMETHYL-CYCLOPROPANE-CARBOXYLIC ACID-(4-FLUOR-3-PHENOXY-BENZYL)-ESTER AND PROCESS FOR PREPARING THE ACTIVE SUBSTANCE

AGENT WITH INSECTICIDAL AND ACARICIDAL EFFECT COMPRISING 3-ALKEN-1-YL-2,2-DIMETHYL-CYCLOPROPANE-CARBOXYLIC ACID-(4-FLUOR-3-PHENOXY-BENZYL)-ESTER AND PROCESS FOR PREPARING THE ACTIVE SUBSTANCE

机译:包含3-烯-1-基-2,2-二甲基-环丙烷-羧酸-(4-氟-3-苯氧基-苄基)-酯的杀虫和杀螨作用的制剂及其制备活性物质的方法

摘要

4-Fluoro-3-phenoxy-benzyl 3-alken-1-yl-2,2-dimethylcyclopropanecarboxylates have the general formula IMAGE (I) wherein R represents alkyl or alkenyl, R1 represents hydrogen or alkyl, with the proviso that R and R1 are different, and R2 represents hydrogen, cyano or alkyl, alkenyl or alkynyl having in each case up to 4 carbon atoms, are obtained if 3-alken-1-yl-2,2-dimethyl-cyclopropanecarboxylic acids of the general formula IMAGE (II) wherein R and R1 have the meaning given above, or reactive derivatives of these acids, are reacted with 4-fluoro-3-phenoxy-benzyl alcohols of the general formula IMAGE (III) wherein R2 has the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of an acid acceptor and/or catalyst, and if appropriate using a diluent. The compounds of the formula (I) have a high pesticidal activity, especially against insects or acarids.
机译:4-氟-3-苯氧基-苄基3-烯丙基-1-基-2,2-二甲基环丙烷羧酸酯具有通式<图像>(I),其中R代表烷基或烯基,R1代表氢或烷基,条件是R如果通式的3-烯-1-基-2,2-二甲基-环丙烷羧酸获得,则R 1和R 1不同,R 2代表氢,氰基或烷基,烯基或炔基,它们分别具有至多4个碳原子。将其中R和R1具有上述含义的(II)或这些酸的反应性衍生物与通式(III)的4-氟-3-苯氧基-苄基醇反应,其中R2具有如果合适的话,在酸受体和/或催化剂的存在下,并且如果合适的话,使用稀释剂,则可以具有上述含义,或与这些醇的反应性衍生物。式(I)的化合物具有很高的杀虫活性,尤其是对昆虫或螨类。

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