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LOW-VISCOSE, MICROCAPSULES AND BINDERS CONTAINING AQUEOUS COATING AND PRINTING COLORS, PAPER PRINTED AND COATED WITH THESE COLORS, AND THEIR USE IN PRINT-SENSITIVE COPYING SYSTEMS.
LOW-VISCOSE, MICROCAPSULES AND BINDERS CONTAINING AQUEOUS COATING AND PRINTING COLORS, PAPER PRINTED AND COATED WITH THESE COLORS, AND THEIR USE IN PRINT-SENSITIVE COPYING SYSTEMS.
1. Stable aqueous printing inks and coating compositions of low viscosity containing microcapsules and binders, comprising, in addition to auxiliaries usually used in aqueous printing inks and coating compositions, (a) a water-miscible solvent or solvent mixture having a boiling point of =100 degrees C, and (b) microcapsules having a mean diameter of from 1 to 8 mu m which are obtained by condensation of melamine and formaldehyde or melamine/formaldehyde precondensates in an aqueous dispersion of the solid or liquid, essentially water-insoluble phase forming the core, in an aqueous solution of a homopolymer or copolymer containing sulphonic acid groups, at a pH of from 3 to 6.5 and a temperature of from 20 to 100 degrees C, the molar ratio of melamine to formaldehyde being from 1 : 1.5 to 1 : 6, and the ratio of resin to core material being from 1 : 13 to 1 : 2, and the polymer containing sulphonic acid groups, which is free from phenyl and/or sulphophenyl groups, having a K value according to Fikentscher of from 100 to 170 or a viscosity of from 200 to 5000 mPas at a shear gradient of 489 s**-1 in 20% strength by weight aqueous solution at 25 degrees C.
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机译:1.稳定的低粘度含微胶囊和粘合剂的水性印刷油墨和涂料组合物,除通常用于水性印刷油墨和涂料组合物中的助剂外,还包括(a)沸点为=的与水混溶的溶剂或溶剂混合物<100摄氏度,(b)平均直径为1至8微米的微胶囊,是通过将三聚氰胺和甲醛或三聚氰胺/甲醛预缩合物在固体或液体的水分散体中缩合而制得的,在含有磺酸基的均聚物或共聚物的水溶液中,pH为3至6.5,温度为20至100℃的条件下形成核,三聚氰胺与甲醛的摩尔比为1:1.5至1.5 1:6,树脂与芯材的比例为1:13:1:2,含磺酸基的聚合物,不含苯基和/或磺基苯基,K值为acc在25℃,重量比20%的水溶液中,在489 s **-1的剪切梯度下,按Fikentscher的粘度为100至170或粘度为200至5000 mPas。
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