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Oxydehydrogenation catalyst, and process for the catalytic conversion of isobutyric acid or functional derivatives thereof into corresponding alpha, beta-unsaturated compounds

机译:氧化脱氢催化剂,以及将异丁酸或其功能性衍生物催化转化为相应的α,β-不饱和化合物的方法

摘要

Isobutyric acid or functional derivatives thereof, for example lower alkyl esters, are oxidatively dehydrogenated in order to achieve vapour-phase conversion thereof into the corresponding alpha , beta -ethylenically unsaturated derivative by contact with a heterogeneous catalyst in the presence of molecular oxygen. The catalyst comprises calcined phosphates of iron which contain silver, cobalt, lanthanum or tellurium as modifying or doping component.
机译:异丁酸或其功能衍生物,例如低级烷基酯,被氧化脱氢,以通过在分子氧存在下与非均相催化剂接触而实现其汽相转化为相应的α,β-烯键式不饱和衍生物。该催化剂包含煅烧的铁磷酸盐,其包含银,钴,镧或碲作为改性或掺杂组分。

著录项

  • 公开/公告号CH653005A5

    专利类型

  • 公开/公告日1985-12-13

    原文格式PDF

  • 申请/专利权人 ASHLAND OIL INC.;

    申请/专利号CH19810006706

  • 发明设计人 DANIEL CHELLIAH;BRUSKY PHYLLIS L.;

    申请日1981-10-20

  • 分类号C07C57/04;C07C69/54;B01J27/185;

  • 国家 CH

  • 入库时间 2022-08-22 07:33:28

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