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Process for the preparation of a catalyst for the oxidation of mercaptans to disulfides, and use of this catalyst in the sweetening of petroleum distillates

机译:制备用于将硫醇氧化为二硫化物的催化剂的方法,以及该催化剂在石油馏分的甜化中的用途

摘要

1. A process for manufacturing a catalyst, for oxidizing mercaptans to disulfides, consisting of at least one metal complex (the metal being selected from the group consisting of cobalt, nickel, cooper and zinc) of ethylene diamine tetracetic acid or its sodium salt, said complex being directly fixed on a basic anion exchange resin, the process being characterized by a two-step operation of : (a) forming said metal complex of ethylene diamine tetracetic acid or of its sodium salt by reacting a salt of metal selected from the group consisting of nickel, copper, zinc and cobalt with ethylene diamine tetracetic acid or its sodium salt. (b) exchanging the resultant complex on a basic anion exchange resin.
机译:1.制造用于将硫醇氧化成二硫化物的催化剂的方法,该催化剂由乙二胺四乙酸或其钠盐的至少一种金属配合物(该金属选自钴,镍,铜和锌)组成,所述络合物直接固定在碱性阴离子交换树脂上,该方法的特征在于两步操作:(a)通过使选自乙二胺四乙酸或其钠盐的金属盐反应形成所述金属络合物。镍,铜,锌和钴与乙二胺四乙酸或其钠盐组成的组。 (b)在碱性阴离子交换树脂上交换所得的络合物。

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