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A process for preparing a biaxially stretched polyamide films

机译:一种双轴拉伸聚酰胺薄膜的制备方法

摘要

Biaxially drawn polyamide films having an excellent levelness are prepared as follows. A substantially unoriented polyamide film is heated at 45 DEG -65 DEG C., and then drawn in the longitudinal direction at a deformation rate of at least 10,000%/min. and a draw ratio of 2.7-3.5 by a roll stretcher. The drawn film is immediately transferred to the lateral drawing position at 45 DEG -60 DEG C. within a time (t):t=e(3.9-0.053T1) where e=the base of natural logarithm and T1=film temperature during this period of time (t), which is 45 DEG -60 DEG C. The thickness profile of the film at the starting position of lateral drawing is gradually reduced from the side and portions toward the central portion of the width so that the film thickness at the central portion is 75-90% of the film thickness at the side end portions. The film is drawn in the lateral direction at an average deformation rate of 2,000-10,000%/min. and a draw ratio of 3-5 by a tenter type stretcher in such a manner that, until the mechanically set draw ratio between respective tenter clips exceeds 1.4 times the original distance, the film is expanded at an angle of up to 6 DEG with respect to the travelling direction at a tenter clip temperature T2 (T2T1). The film temperature is elevated stepwise in the lateral drawing and the film temperature at the termination position of lateral drawing is 70 DEG -100 DEG C.
机译:如下制备具有优异流平性的双轴拉伸聚酰胺膜。将基本上未取向的聚酰胺膜在45℃-65℃下加热,然后以至少10,000%/ min的变形率在纵向上拉伸。辊式拉伸机的拉伸比为2.7-3.5。在时间(t):t = e(3.9-0.053T1)(其中e =自然对数的底数,T1 =膜温度)期间,将拉伸的薄膜立即转移到45℃-60℃的横向拉伸位置。时间段(t)为45℃-60℃。在横向拉伸开始位置处的膜的厚度轮廓从宽度的侧面和部分朝向中心逐渐减小,使得在中央部分是侧端部分的膜厚度的75-90%。以2,000-10,000%/ min的平均变形率在横向上拉伸膜。并用拉幅机型拉伸机以3-5的拉伸比,使得在各拉幅机夹之间的机械设定的拉伸比超过原始距离的1.4倍之前,薄膜以相对于最大6°的角度膨胀。在拉幅机夹头温度T2(T2

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