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Process for the production of polymers of a - olefins highly stereo - regular, and the catalyst used for the implementation of this

机译:生产高度立构规整的α-烯烃聚合物的方法,以及用于实施该催化剂的催化剂

摘要

This process consists in homopolymerize or copolymerized a a - olefin containing 3 has 10atomes of carbon with other olefins or with the ethylene, using a catalyst comprising three elements a, b and c: a. a catalyst obtained by reaction between a solid product, a group of compounds iii comprising a link o - co, one element selected from among the links c - o - h, c - o - c, c - n, n, n - o - c, p - o - c, p - n - c, c - (s) - h, c - s - c, s - o - c and p - s - c, and titanium with a link halogen, the solid product being obtained by reaction of a organo - magnesian with a compound of formula rsix halogeno - silica, r is a group hydrocarbon, x represents an atom of halogen and n is defined by the equation on4, ii, halogeno - aluminium compound of formula ralx, r is a group hydrocarbon, x is an atom of halogen and l is defined by the equation ol3, b. an activating agent of formula raly, r is a group hydrocarbon, an atom of halogen or of 1996 and m is defined by the equation 2m3, c. at least one donor for the electrons.
机译:该方法在于使用包含三种元素a,b和c的催化剂,使含有3个具有10个原子的碳的α-烯烃与其他烯烃或与乙烯进行均聚或共聚。一种通过固体产物,一组包含链接o-co,选自链接c-o-h,c-o-c,c-n,n,n-o的元素的化合物iii之间的反应获得的催化剂-c,p-o-c,p-n-c,c-(s)-h,c-s-c,s-o-c和p-s-c,以及带有卤素原子的钛,固体通过有机镁与式rsix卤代-二氧化硅化合物反应获得的产物,r是基团烃,x代表卤素原子,n由式on4定义,ii,式ralx的卤代-铝化合物,r是烃基,x是卤素原子,l由等式ol3,b定义。式raly的活化剂,r是烃基,是卤素原子或原子团为1996的原子,m由式2m 3定义,c。至少一个电子供体。

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