Polymeric materials are repolymerized by intensely admixing the polymer with an additive having the formula: CHEM wherein M is titanium or zirconium, R, R1 and R2 are each a monovalent alkyl, alkenyl, alkynyl, aralkyl, aryl or alkaryl group having up to 20 carbon atoms or a halogen or ether substituted derivative thereof, and, in addition, R2 may also by an oxy derivative or an ether substituted oxy derivative of said groups; A, B, and C are each a monovalent aroxy, thioaroxy, diester phosphate, diester pyrophosphate, oxyalkylamino, sulfonyl or carboxyl containing up to 30 carbon atoms; and a + b + c = 3. The repolymerized polymers have improved physical properties and higher heat distortion temperatures, experience less thermal degradation and show greater solvolysis resistance than the polymers prior to the repolymerization.
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机译:通过将聚合物与具有以下化学式的添加剂强烈混合来重新聚合聚合物材料:其中M是钛或锆,R,R 1和R 2分别是一价烷基,烯基,炔基,芳烷基,芳基R 2还可为具有至多20个碳原子的烷芳基或其卤素或醚取代的衍生物,另外,R 2也可为所述基团的氧衍生物或醚取代的氧衍生物。 A,B和C分别是单价的芳氧基,硫代芳氧基,磷酸二酯,焦磷酸二酯,氧烷基氨基,磺酰基或含至多30个碳原子的羧基;和a + b + c =3。与再聚合之前的聚合物相比,再聚合的聚合物具有改善的物理性能和较高的热变形温度,热降解较小,并且显示出更高的耐溶剂分解性。
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