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PROCESS FOR MICROENCAPSULATING HYDROPHOBIC OILS, THE MICROCAPSULES OBTAINED AND THE USE THEREOF

机译:微胶囊化疏水性油的过程,获得的微囊及其用途

摘要

1. Process for microencapsulating hydrophobic oils with colour reactants of colour reaction systems dissolved therein, a cationized melamine/formaldehyde precondensate being precipitated in ultra-fine suspension from its acid aqueous solution, accompanied by vigorous stirring and by modifying the solubility conditions, said suspension is mixed under vigorous stirring with a hydrophobic oil containing the colour reactants in dissolved form, the oil-in-water dispersion obtained is acid-adjusted and an aqueous solution of a water-soluble, non-ionic melamine/formaldehyde precondensate is added, accompanied by stirring, for forming the microcapsule envelope, characterized in that, for stabilizing the oil-in-water dispersion, the pH-value of the acid aqueous solution of a cationized melamine/formaldehyde precondensate which, in the weak acid, neutral and alkaline aqueous use range is present in insoluble cationizable form, is raised in the absence of water-soluble organic polymers by the addition of Bronsted bases and accompanied by vigorous stirring to such an extent that the cationizable melamine/formaldehyde precondensate is precipitated in ultra-fine suspension as a result of the modified solubility conditions.
机译:1.用溶解于其中的颜色反应体系的颜色反应物将疏水性油微囊化的方法,将阳离子化的三聚氰胺/甲醛预缩合物从其酸性水溶液中以超细悬浮液沉淀出来,伴随剧烈搅拌并通过改变溶解度条件,所述悬浮液为在剧烈搅拌下与含有溶解形式的彩色反应物的疏水油混合,调节所得的水包油分散体的酸,并添加水溶性非离子型三聚氰胺/甲醛预缩合物的水溶液,并伴随着搅拌,以形成微胶囊包膜,其特征在于,为了稳定水包油分散体,在弱酸,中性和碱性水溶液中使用阳离子化三聚氰胺/甲醛预缩合物的酸性水溶液的pH值该范围以不溶性阳离子化形式存在,通过添加不存在水溶性有机聚合物而提高布朗斯台德碱的加入并伴随剧烈搅拌,以至于由于修饰的溶解度条件,可阳离子化的三聚氰胺/甲醛预缩合物沉淀在超细悬浮液中。

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