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POLYESTER POLYURETHANES CONTAINING TERMINAL HYDROXY GROUPS, AND THEIR USE AS AN ADHESIVE OR FOR THE PREPARATION OF ADHESIVES

机译:聚酯聚酯,含末端羟基基团,可作胶粘剂或用于制备粘合剂

摘要

1. Substantially linear polyester polyurethanes containing hydroxyl end groups, prepared by the reaction of a) polyester diols having a molecular weight above 600 and optionally b) diols in the molecular weight range of from 62 to 600 as chain lengthening agents with c) organic diisocyanates in proportions corresponding to an equivalent ratio of hydroxyl groups of components a) and b) to isocyanate groups of component c) in the range of from 1:0.9 to 1:0.999, characterized in that at least 80 % by weight of component a) consists of polyester diols in the molecular weight range of from 4000 to 6000 based on (i) adipic acid and (ii) mixtures of 1,4-dihydroxybutane and 1,6-dihydroxyhexane in a molar ratio of diols of from 4:1 to 1:4.
机译:1.基本上线性的含有羟基端基的聚酯聚氨酯,其通过以下方法制备:a)具有大于600的分子量的聚酯二醇和任选的b)作为链增长剂的分子量为62至600的二醇与c)有机二异氰酸酯的反应其比例对应于组分a)和b)的羟基与组分c)的异氰酸酯基的当量比为1∶0.9至1∶0.999,其特征在于组分a)的重量至少为80%。由基于(i)己二酸和(ii)1,4-二羟基丁烷和1,6-二羟基己烷的摩尔比为4:1的聚酯二醇组成,分子量为4000至6000 1:4

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