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Process for renovating a facade window consisting of a single large window unit or a plurality of smaller window units

机译:翻新由单个大窗户单元或多个小窗户单元组成的立面窗户的方法

摘要

A novel graft copolymer capable of imparting to a polyolefin when blended therewith a good balance of tensile modulus, sag resistance and melt viscosity, is a polyolefin trunk having a, preferably relatively high weight-average molecular weight, methacrylate polymer chain grafted thereto. The graft copolymer is formed by dissolving a non-polar polyolefin in an inert hydrocarbon solvent, and, while stirring the mixture, adding methacrylate monomer together with initiator to produce a constant, low concentration of radicals, and covalently graft a polymer chain, preferably of relatively high molecular weight, to the polyolefin backbone. The graft copolymer can be separated from the solvent, by volatilizing the solvent, for example in a devolatilizing extruder, and pelletised or extruded or otherwise shaped into a desired shape such as a sheet, tube or the like. This graft copolymer can be blended with a polyolefin matrix to improve its physical properties in the melt, upon cooling, and in the solid state, and is useful in cast and oriented films, solid extruded rod and profile, foamed rod, profile and sheet and blown bottles. The graft copolymer can also be used to improve compatibility between polymers in a wide range of polymer blends.
机译:一种新型的接枝共聚物,当与聚烯烃共混时能赋予其拉伸模量,抗流挂性和熔体粘度的良好平衡,是一种接枝有,优选重均分子量较高的甲基丙烯酸酯聚合物链的聚烯烃主干。通过将非极性聚烯烃溶解在惰性烃溶剂中,并在搅拌混合物的同时,将甲基丙烯酸酯单体与引发剂一起添加以产生恒定的低浓度自由基,并共价接枝聚合物链,优选由以下物质形成接枝共聚物:相对较高的分子量,以聚烯烃为主链。可以通过例如在脱挥发分的挤出机中使溶剂挥发而使接枝共聚物与溶剂分离,然后将其造粒或挤出或以其他方式成形为所需的形状,例如片,管等。该接枝共聚物可以与聚烯烃基体共混,以改善其在熔融状态,冷却后和固态时的物理性能,并适用于流延和定向薄膜,固体挤出的棒材和型材,发泡棒材,型材和片材以及吹瓶。接枝共聚物还可以用于改善多种聚合物共混物中聚合物之间的相容性。

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