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Poly 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylic esters useful as thermal stabilizers for synthetic polymers and processes for their preparation

机译:用作合成聚合物热稳定剂的聚1,4-二氢-2,6-二甲基吡啶-3,5-二羧酸酯及其制备方法

摘要

Poly-dihydro-2,6-dimethylpyridine-3,5-dicarboxylesters of general formula (I) IMAGE IMAGE +TR IMAGE in which A, B, m, n, k, j, R, R1 and R2 have the meanings defined in the text, useful as thermal stabilizers for synthetic polymers, in particular for polyvinylchloride-based masses. The compounds of formula (I) are preferably used in combination with the usual stabilizers based on organic metal derivatives. They can also be used combined with agents which exert a synergic action in maintaining a low color of manufactured articles subjected to heating, and in particular with betadicarbonyl compounds of formula (II): R3-CO-CH2-CO-R4 (II) in which R3 and R4 have the meanings defined in the text, in masses containing organic calcium and zinc salts as basic stabilizers.
机译:通式(I)的聚二氢-2,6-二甲基吡啶-3,5-二羧基酯 + TR 其中A,B,m,n,k,j,R,R1和R 2具有本文定义的含义,可用作合成聚合物,特别是基于聚氯乙烯的物质的热稳定剂。式(I)化合物优选与基于有机金属衍生物的常规稳定剂组合使用。它们还可以与在维持加热的制品中的低颜色方面发挥协同作用的试剂一起使用,特别是与式(II)的β-二羰基化合物:R3-CO-CH2-CO-R4(II)组合使用。在含有有机钙和锌盐作为碱性稳定剂的物质中,R 3和R 4具有本文所定义的含义。

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