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HYDROGEN OCCLUDED ALLOY-BASED HEAT APPLICATION SYSTEM

机译:基于氢封堵合金的热力应用系统

摘要

PURPOSE:To maintain the safety easily and prevent an increase in the loss of sensible heat by turning a first hydrogen occluded alloy and a second hydrogen occluded alloy into an alloy having a specified working pressure during a regeneration process. CONSTITUTION:MH1 and MH2 are adapted to comprise an alloy whose working pressure is 20atm or below. As for the MH1 or MH2, their minimum differential pressure required to absorb and discharge reversibly hydrogen gas whose effective hydrogen transfer volume is 0.6wt and over, is arranged to be 0.8 or below in terms of a differential natural logarithm. Furthermore, the MH1 is hydrogen occluded alloy in MgZn2 type Laves phases structure which contains Zr, M, and Co while the MH2 is a hydrogen occluded alloy in AB5 type hexcrystal structure which contains rare earth elements, Ni, and a first transfer metal element and selectively contains at least one element out of Al and Sn. When the MH1 for a vessel 1 is cooled and maintained at an ambient temperature and an ON/OFF valve 8 is opened, the MH2 for a vessel 4 discharges hydrogen, transfers the hydrogen to the MH1 from a transfer channel 6 so that it may be absorbed while the MH2 itself generates cold heat at a temperature of about minus 35 by endothermic action induced by discharged reaction, and gives the generated heat to refrigerating load 13 by way of a heat exchanger 5.
机译:目的:通过在再生过程中将第一氢吸藏合金和第二氢吸藏合金转变为具有指定工作压力的合金,轻松维护安全并防止显热损失增加。组成:MH1和MH2适合于包含一种工作压力为20atm或更低的合金。至于MH 1或MH 2,其吸收和排出可逆氢的氢气的最小压差按有效自然对数计算为0.8或以下,该最小压差可逆地吸收和排出有效氢转移量为0.6wt及以上。此外,MH1是包含Zr,M和Co的MgZn2型Laves相结构中的氢吸藏合金,而MH2是AB5类六方晶结构中的氢吸藏合金,其中包含稀土元素,Ni和一次转移金属元素,并且选择性地包含Al和Sn中的至少一种元素。当将用于容器1的MH1冷却并保持在环境温度并且打开/关闭阀8时,用于容器4的MH2排出氢,将氢从传输通道6转移至MH1,从而可以MH2自身通过由排出的反应引起的吸热作用而在大约负35的温度下产生冷热而被吸收,并且通过热交换器5将所产生的热提供给制冷负载13。

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