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Synthetic organic polymers for the selective flocculation of titanium and iron ores

机译:钛和铁矿选择性絮凝的合成有机聚合物

摘要

Flucculating agents for the selective flocculation of ultra­fine granulometry titanium and iron ores suspended in water, said agents being made up of polymeric or copolymeric compounds contain­ing as the monomeric units and monomers of formula I where R¹ and R², which can be the same or different, represent a -O-CHR⁵-O-bridge, or two hydroxyl groups which can also be in the form of their ether or ester derivatives, and in which formula one of the symbols R³, R⁴ or R⁵ corresponds to an atomic group contain­ing, at a position variously spaced from the substitution site, a polymerizable system which is preferably an olefinic system activated with respect to polymerization reactions, whereas the other symbols, which can be the same or different, can be hydrogen atoms or alkyl, aryl, hydroxyl, alkoxyl, hydroxyalkyl, alkoxyalkyl, haloalkyl, carbonyl, carboxyl, ester, amido, nitrilo, or sulfonic groups, or halogen atoms or nitro groups.;The copolymerizable comonomers which can be copolymerized with said monomers of formula I are made up of olefinic compounds which are active towards polymerization reactions and contain groups whose hydrophilic character changes with the pH values.
机译:用于选择性絮凝悬浮在水中的超细粒度钛和铁矿石的絮凝剂,所述絮凝剂由含有式I的单体单元和单体的聚合或共聚化合物组成 其中R 1和R 2可以相同或不同,代表-O-CHR 4 -O-桥或两个羟基,也可以其醚或酯衍生物的形式存在,式中的符号之一R 3,R 5或R 6对应于在与取代位点不同距离的位置上含有一个可聚合体系的原子团,该体系最好是针对聚合反应而活化的烯烃体系,而其它符号可以相同或不同。可以是氢原子或烷基,芳基,羟基,烷氧基,羟烷基,烷氧基烷基,卤代烷基,羰基,羧基,酯,酰胺基,腈基或磺酸基团或卤素原子或硝基基团;可与之共聚的可共聚单体所述式I的单体由对聚合反应有活性的烯烃化合物组成,并含有亲水性随pH值变化的基团。

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