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A filtration membrane material having excellent organic solvent resistance, a method for forming the filtration membrane, and a method for producing a bismaleimide-based polymer used in a filtration membrane material
A filtration membrane material having excellent organic solvent resistance, a method for forming the filtration membrane, and a method for producing a bismaleimide-based polymer used in a filtration membrane material
A membrane filter material formed from a solvent resistant bismaleimide polymer which is formed by polymerizing a bismaleimide compound with a perhydrodiaza-type heterocyclic compound and has a main structural skeleton represented by the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a lower carbon chain which is linear or contains a methyl group or ethyl group on the side chain, R.sub.5 represents a divalent group containing an aromatic ring, Y is R or N--R--N in which R is a lower carbon chain, and m is 0 or 1.PPThis bismaleimide polymer can be a membrane filter material having an excellent organic solvent resistance. When this polymer is formed into a hollow fiber or plain film, a high separating and filtering capacity and an excellent organic resistance can be attained. A membrane filter material having an enhanced organic solvent resistance is provided by preparing the bismaleimide polymer by reacting the bismaleimide compound and perhydrodiaza-type heterocyclic compound in a halogen-containing organic solvent in the presence of a small amount of a phenol.
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机译:由耐溶剂性双马来酰亚胺聚合物形成的膜过滤器材料,其是通过将双马来酰亚胺化合物与过氢重氮型杂环化合物聚合而形成的,其主要结构骨架由下式表示:其中R1, R 2,R 3和R 4表示直链或在侧链上含有甲基或乙基的低碳链,R 5表示含有芳族化合物的二价基团环,Y为> R <或> NR–N <,其中R为低碳链,m为0或1。该双马来酰亚胺聚合物可以是具有优异的耐有机溶剂性。当将该聚合物制成中空纤维或平膜时,可以获得高的分离和过滤能力以及优异的耐有机性。通过使双马来酰亚胺化合物和过氢重氮型杂环化合物在少量的苯酚存在下在含卤素的有机溶剂中反应来制备双马来酰亚胺聚合物,从而提供具有增强的耐有机溶剂性的膜过滤材料。
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