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Hydrides of the plate structure deck, their process of preparation and their application for the catalysis of chemical reactions

机译:板状结构甲板的氢化物,其制备方法及其在化学反应催化中的应用

摘要

Hydrides of the plate of the bimetallic bridged structure. / p & & p & they are represented by the general formula: & br / (see appended drawing in bopi) & br / in which: / p & & p & - m is a metal in the state of valence n at least equal to 2, 1 / p & & p & - x is a halogen atom, and / p & & p & - p p is a schematic representation of a ligand of general formula: & br / (see appended drawing in bopi) & br / / p & & p & in which: / p & & p. R1, r2, r5 and r6 are identical or different, are chosen from among the aliphatic or cycloaliphatic hydrocarbon radical having from 1 to 8 carbon atoms and the aromatic hydrocarbon radical having from 6 to 10 carbon atoms, 1 / p & & p. R3 and r4 are identical or different, are chosen from among the hydrogen atom and the aliphatic hydrocarbon radicals, having from 1 to 8 carbon atoms, the case may be functionalized and / or together forming a cycle, and / p & & p & m is an integer greater than or equal to 4. / p & & p & the application of a hydride such as component of the catalytic system used to catalyse a chemical reaction.
机译:双金属桥接结构的板的氢化物。 & &它们由通式表示:& br />(请参阅bopi中的附图)& br />其中: & & -m是价态n至少等于2的金属,<1 / p>。 & & -x是卤素原子,并且& & -pp是通式的配体的示意图: br />(请参阅bopi中的附图)& br /> 。 R 1,r 2,r 5和r 6相同或不同,选自具有1至8个碳原子的脂族或脂环族烃基和具有6至10个碳原子的芳族烃基。 & p>。 R 3和r 4相同或不同,选自氢原子和具有1至8个碳原子的脂族烃基,该壳可以被官能化和/或一起形成一个环。 & & m是大于或等于4的整数。 & &氢化物的应用,例如用于催化化学反应的催化体系的组成部分。

著录项

  • 公开/公告号FR2635317B1

    专利类型

  • 公开/公告日1990-10-19

    原文格式PDF

  • 申请/专利权人 NORSOLOR;

    申请/专利号FR19880010820

  • 发明设计人 ANDRE MORTREUX;ERIC PAUMARD;FRANCIS PETIT;

    申请日1988-08-11

  • 分类号C01B6/02;B01J31/12;C07C47/228;

  • 国家 FR

  • 入库时间 2022-08-22 06:09:24

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