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Method of producing an adsorbent from bloating minerals and calcium sulfate hemihydrate

机译:由膨胀的矿物和半水硫酸钙生产吸附剂的方法

摘要

The invention relates to a method of producing an adsorbent where an expanded granular bloating mineral and calcium sulfate hemihydrate are mixed to form a granulated material where the calcium sulfate hemihydrate is converted in toto into calcium sulfate dihydrate by the addition of a surplus of water, and where the free water is removed by drying. It is desirable that the proportion of bloating mineral be reduced, that the adsorption effect be substantially retained and the hardness of the adsorbent be increased without any additives. This is accomplished by mixing calcium sulfate hemihydrate and bloating mineral in such proportion that a weight ratio of calcium sulfate: bloating minerals 5:1 and up to 10:1 exists in the adsorbent, in that mixing is effected by calcium sulfate hemihydrate and the bloating mineral being poured together into a tank and mixed there together by a stirring tool to form a granulated mixture, in that the granulated mixture after the addition of the water and before drying is allowed a retention time of at least 4 minutes, and in that the dry calcium sulfate dihydrate is converted by calcining at 120-150 C. in such a proportion into calcium sulfate hemihydrate that the adsorbent has a total water content of 1% by weight to 16% by weight. The adsorbent produced in this manner comprises, on the one hand, open-pore smaller particles which consist only of calcium sulfate and, on the other hand, open-pore larger particles where a bloating mineral core is coated with calcium sulfate.
机译:本发明涉及一种吸附剂的制造方法,其中将膨胀的颗粒状膨胀的矿物和半水硫酸钙混合以形成粒状材料,其中通过添加过量的水将半水硫酸钙转化为二水合硫酸钙,以及干燥除去游离水。理想的是减少膨胀性矿物的比例,基本上保持吸附效果,并且在没有任何添加剂的情况下增加吸附剂的硬度。这是通过将半水合硫酸钙和气胀性矿物以一定比例混合来实现的,以使吸附剂中存在硫酸钙:气胀性矿物的重量比> 5:1且高达10:1,因为混合是通过半水合硫酸钙和将膨胀的矿物质一起倒入罐中,并通过搅拌工具在其中混合以形成粒状混合物,这是因为在加入水之后且干燥之前,粒化混合物的保留时间至少为4分钟,并且通过在120-150℃下煅烧将干燥的二水合硫酸钙以一定比例转化成半水合硫酸钙,使得吸附剂的总水含量为1重量%至16重量%。以这种方式产生的吸附剂一方面包括仅由硫酸钙组成的开孔较小的颗粒,另一方面包括其中膨胀的矿物芯被硫酸钙包覆的开孔较大的颗粒。

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