首页> 外国专利> AQUEOUS ELECTROPHORETIC ENAMELLING BATHS FOR CATHODIC ELECTROPHORETIC ENAMELLING, AND PROCESS FOR THEIR PRODUCTION

AQUEOUS ELECTROPHORETIC ENAMELLING BATHS FOR CATHODIC ELECTROPHORETIC ENAMELLING, AND PROCESS FOR THEIR PRODUCTION

机译:用于阴极电泳搪瓷的水性电泳搪瓷浆及其生产工艺

摘要

Electrophoretic enamelling baths as described, which contain modified epoxy amine additives as cathodically separable binders and which are produced (1) by causing (A) polyepoxides and (B) compounds containing one or several, preferably 2, hydroxyl groups per molecule bound to aromatic and/or (cyclo)aliphatic molecule fragments, to react in the presence of amine basic catalysts, to form epoxy-group containing intermediates and (2) by then causing these intermediates to react as applicable with other customary modification compounds and finally with (C) primary and/or secondary (poly)amines, whereby the reaction products thus obtained are neutralized with acids, are dispersed in an aqueous medium and this dispersion is reprocessed using well-known methods to produce electrophoretic enamelling baths. The electrophoretic enamelling baths of the invention are characterized in that the reaction products formed from (A), (B) and (C) are dispersed in an aqueous medium and then at least one anion exchanger reactive to chloride ions is added to the dispersion thus obtained, such exchanger being separated after completion of the exchange reaction.
机译:所述的电泳涂漆浴,其包含改性的环氧胺添加剂作为可阴极分离的粘合剂,并且是通过以下方式制得的:(1)通过使(A)多环氧化物和(B)每分子与芳族化合物结合并含有一个或多个(优选2个)羟基的化合物而制得(或)(环)脂族分子片段,在胺碱性催化剂的存在下反应,形成含环氧基的中间体,和(2),然后使这些中间体与其他常用的改性化合物(最后与(C))反应将由此获得的反应产物用酸中和的伯和/或仲(聚)胺分散在水性介质中,并使用众所周知的方法对该分散体进行再加工,以制备电泳漆包埋浴。本发明的电泳涂漆浴的特征在于,将由(A),(B)和(C)形成的反应产物分散在水性介质中,然后将至少一种对氯离子具有反应性的阴离子交换剂加入到分散体中,从而在交换反应完成后,分离出这种交换剂。

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