首页> 外国专利> Process for stabilizing a solution of aqueous hydrogen peroxido of concentrated acid solution, aqueous, concentrated.Of peroxido of hydrogen and process for stabilisation or a solution of peroxigenio stabilized

Process for stabilizing a solution of aqueous hydrogen peroxido of concentrated acid solution, aqueous, concentrated.Of peroxido of hydrogen and process for stabilisation or a solution of peroxigenio stabilized

机译:稳定浓酸溶液,过氧化氢水溶液,过氧化氢水溶液的方法,氢过氧化物的稳定化方法或过氧化原稳定溶液

摘要

Concentrated solutions of hydrogen peroxide tend to decompose on storage, thereby losing their effectiveness, amongst other reasons by virtue of interaction with contaminating transition metals.;Peroxygen compounds are stabilised by contact with a stabilising amount of compound of general formula:- in which X represents a methylene phosphonic acid group of formula -CH₂-(-PO₃H₂) or salt thereof, R represents a tetra methylene diradical, optionally alkyl-substituted, that completes a cyclo-aliphatic ring and thereby establishes the two NX₂ groups in a substantially fixed configuration and Y represents a hydrogen or lower alkyl group.;Preferably, the solutions contain additionally one or more co-stabilisers, including stannate, phosphates, hydroxybenzoic acid, citric acid and nitrate.;The stabiliser system can enable the solution to be diluted, even with municipal water.
机译:过氧化氢的浓溶液易于在储存时分解,从而由于与污染的过渡金属的相互作用等原因而失去其效力。过氧化合物通过与稳定量的通式化合物接触而稳定: 其中X代表式-CH 2-(-PO 3 H 2)的亚甲基膦酸基团或它的盐,R代表四亚甲基双自由基,可被烷基取代,它完成一个环脂环并在其中形成两个NX 2基团。基本代表固定构型,Y代表氢或低级烷基。;优选地,溶液还包含一种或多种助稳定剂,包括锡酸酯,磷酸盐,羟基苯甲酸,柠檬酸和硝酸盐。稀释,甚至用市政用水稀释。

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