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N-substituted carbamoyllactam functional compounds and polylactam block copolymers derived therefrom

机译:N-取代的氨基甲酰基内酰胺功能化合物和由其衍生的聚内酰胺嵌段共聚物

摘要

Disclosed are conversion products of N-substituted carbamoyllactam functional compounds characterized by the general formula: where:A represents an oxygen atom or an NH group;R represents an alkyl, aralkyl, alkaryl or aryl group, where alkyl and alkyl bound in aralkyl or alkaryl may also be cycloalkyl;P represents a residue of a compound P(AH)x with a number average molecular weight of at least 150, with one or more OH or NH₂ groups, P(AH)x being a liquid crystalline compound or a compound with liquid crystalline segments in the main chain and/or the side chain, or a compound which forms with lactam-­blocked polyisocyanate a compound with liquid crystalline properties;(-L-) represents an opened lactam ring;(-L) represents a non-opened lactam ring;x is a whole number higher than or equal to 1;y is equal to 0 or 1; anda is a whole number higher than or equal to 1.;Further, the present invention relates to polylactam block copolymers obtained by lactam polymerization at a lactam group.
机译:公开了具有以下通式的N-取代的氨基甲酰基内酰胺官能化合物的转化产物: <图像文件=“ IMGA0001.GIF” he =“ 22” id =“ ia01” imgContent =“ chem” imgFormat =“ GIF” wi =“ 145” /> 其中:A代表氧原子或NH基团;R代表烷基,芳烷基,烷芳基或芳基,其中结合在芳烷基或烷芳基中的烷基和烷基也可以是环烷基;P代表数均分子量至少为150的具有一个或多个OH或NH 2基团的化合物P(AH) x 的残基,P(AH) x 是液晶化合物或在主链和/或侧链中具有液晶链段的化合物,或与内酰胺封端的多异氰酸酯形成具有液晶性质的化合物的化合物;(-L-)代表打开的内酰胺环;(-L)代表未打开的内酰胺环;x是一个大于或等于1的整数;y等于0或1;和a是大于或等于1的整数。此外,本发明涉及通过在内酰胺基团上的内酰胺聚合获得的聚内酰胺嵌段共聚物。

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