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Process for the activation of halogenated catalysts, catalysts obtained by this process and application of these catalysts in hydrocarbon conversion processes

机译:卤化催化剂的活化方法,通过该方法获得的催化剂以及这些催化剂在烃转化方法中的应用

摘要

A process for the preparation and activation of a catalyst, comprising a stage of manufacture of a support consisting at least partially of at least one refractory inorganic oxide, a stage of deposition on the said support of at least one metal of the platinum lode, and a stage intended for the formation on the support of at least two metal halides of the Lewis acid type. …??According to the invention, between the deposition of the said metal halides of the Lewis acid type and the use of the catalyst in the reactor, the catalyst is subjected to an activation stage by being maintained in an acidic and nonoxidising or reducing medium at a temperature of between 300 and 475 DEG C so that its final content of promoting metal of the zirconium, molybdenum, tungsten or titanium type is between 0.15 and 1% relative to the weight of the support.
机译:一种催化剂的制备和活化的方法,包括至少部分由至少一种难熔无机氧化物组成的载体的制造阶段,在所述载体上沉积至少一种铂金矿金属的阶段,以及用于在载体上形成至少两种路易斯酸类型的金属卤化物的阶段。根据本发明,在所述路易斯酸类型的金属卤化物的沉积与在反应器中使用催化剂之间,催化剂通过保持在酸性和非氧化或非氧化状态而经历活化阶段。还原介质的温度在300至475℃之间,因此其相对于载体重量的锆,钼,钨或钛类型的促进金属的最终含量为0.15至1%。

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