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PRODUCTION OF HEAT-SENSITIVE POLYACRYLAMIDE DERIVATIVE HAVING ULTRAHIGH MOLECULAR WEIGHT
PRODUCTION OF HEAT-SENSITIVE POLYACRYLAMIDE DERIVATIVE HAVING ULTRAHIGH MOLECULAR WEIGHT
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机译:具有超高分子量的热敏性聚丙烯酰胺衍生物的生产
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摘要
PURPOSE:To obtain the subject polymer having high strength and losing the water-solubility with heat by adding a cationic surfactant to an aqueous solution of a specific acrylamide-type vinyl compound and radically polymerizing the monomer at a specific temperature. CONSTITUTION:The objective polymer having a molecular weight corresponding to an intrinsic viscosity of 2-6 at 27 deg.C as a THF solution can be produced by adding a cationic surfactant or an anionic surfactant at a concentration above the critical micelle concentration to an aqueous solution of an acrylamide- type vinyl compound (e.g. acrylamide) capable of forming a homopolymer exhibiting thermally reversible hydrophilic-hydrophobic dissolution characteristics and radically (co)polymerizing the monomer at a temperature above the cloud point of the resultant aqueous solution of (co)polymer. The above surfactant is preferably trimethylstearylammonium chloride or sodium dodecylbenzenesulfonate.
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