首页> 外国专利> METHOD OF MANUFACTURING FLEXIBLE POLYURETHANE FOAM HAVING VISCOELASTICITY AND STRUCTURAL ACOUSTIC DAMPING CHARACTERISTIC AND NEW POLYOXYALKYLENE/ POLYOL MIXED COMPOSITION WHICH CAN BE USED THEREFOR

METHOD OF MANUFACTURING FLEXIBLE POLYURETHANE FOAM HAVING VISCOELASTICITY AND STRUCTURAL ACOUSTIC DAMPING CHARACTERISTIC AND NEW POLYOXYALKYLENE/ POLYOL MIXED COMPOSITION WHICH CAN BE USED THEREFOR

机译:具有弹性和结构声阻尼特性的柔性聚氨酯泡沫的制备方法以及可以使用的新型聚氧乙烯/多元醇混合组合物

摘要

The invention relates to a process for the production of flexible, soft polyurethane foams having viscoelastic, structure borne soundproofing properties in a temperature range of from -20 DEG C to +80 DEG C, by reacting a) a polyoxyalkylene-polyol mixture containing ai) a block polyoxypropylene-polyoxyethylene-polyol mixture having a hydroxyl number of from 14 to 65 and containing from 2 to 9 % by weight, based on the weight of the polyoxypropylene units, of terminally bonded ethylene oxide units, and prepared by anionic polymerisation at elevated temperature of 1,2-propylene oxide onto an initiator molecule mixture having a mean functionality of from 2.3 to 2.8 comprising water and glycerol and/or trimethylolpropane, and polymerisation of ethylene oxide onto the resultant polyoxypropylene adduct, and aii) at least one difunctional and/or trifunctional polyoxypropylene-polyoxyethylene-polyol containing from 60 to 85 % by weight, based on the total weight of polymerised alkylene oxide units, of oxyethylene units, and having a hydroxyl number of from 20 to 80, and b) optionally low-molecular-weight chain extenders with c) organic and/or modified organic polyisocyanates, in the presence of d) catalysts, e) blowing agents, preferably water, and optionally f) assistants and/or additives, and to the polyoxyalkylene-polyol mixtures (a) which can be used for this purpose.
机译:本发明涉及通过使a)包含ai)的聚氧化烯-多元醇反应,生产在-20℃至+ 80℃的温度范围内具有粘弹性的结构传声的隔音性能的软质软聚氨酯泡沫的方法。一种嵌段聚氧丙烯-聚氧乙烯-多元醇混合物,其羟基数为14至65,且含有基于聚氧丙烯单元重量的2至9重量%的末端键合的环氧乙烷单元,并通过在高温下进行阴离子聚合制备将1,2-环氧丙烷在包含水和甘油和/或三羟甲基丙烷的平均官能度为2.3至2.8的引发剂分子混合物上加热,并将环氧乙烷聚合到所得的聚氧化丙烯加合物上,以及aii)至少一种双官能和/或三官能聚氧丙烯-聚氧乙烯-多元醇,基于聚合的亚烷基的总重量计为60-85%环氧乙烷单元,羟基数为20至80的二甲苯单元和b)可选的低分子量扩链剂,以及c)在d)催化剂存在下,有机和/或改性的有机多异氰酸酯,e)发泡剂,优选水,和任选的f)助剂和/或添加剂,以及可用于该目的的聚氧化烯-多元醇混合物(a)。

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