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PROCESS OF ETHYLENE POLYMERIZATION OR CO-POLYMERIZATION THEREOF WITH ALPHA-OLEFINS IN A FLUIDIZED BED AND IN THE PRESENCE OF A CHROMIUM-BASED CATALYST
PROCESS OF ETHYLENE POLYMERIZATION OR CO-POLYMERIZATION THEREOF WITH ALPHA-OLEFINS IN A FLUIDIZED BED AND IN THE PRESENCE OF A CHROMIUM-BASED CATALYST
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机译:在流化床中和存在铬基催化剂的情况下,乙烯与α-烯烃的聚合或共聚合过程
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摘要
The present invention relates to a process for the polymerisation of ethylene or copolymerisation of ethylene and at least one other alpha-olefin, in the gas phase in a fluidised bed reactor, in the presence of a catalyst comprising chromium compounds associated with a granular support comprising a refractory oxide and activated by thermal treatment, which process is characterised in that the catalyst is used in the form of active particles of prepolymer, obtained by bringing the said catalyst in contact with ethylene, alone, or in a mixture with at least one higher alpha-olefin, in such a way that the prepolymer contains from 4x10-5 to 3 milligram atoms of chromium in the catalyst per gram.
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