首页> 外国专利> Process for the starting of the polymerization of ethylene or copolymerization of ethylene and at least one other alpha-olefin in the gas phase in the presence of a catalyst based on chromium oxide

Process for the starting of the polymerization of ethylene or copolymerization of ethylene and at least one other alpha-olefin in the gas phase in the presence of a catalyst based on chromium oxide

机译:在基于氧化铬的催化剂存在下,在气相中开始乙烯聚合或乙烯与至少一种其他α-烯烃共聚的方法

摘要

The present invention relates to a process for starting up the polymerization of ethylene or copolymerization of ethylene and at least one other alpha-olefin by bringing ethylene and optionally at least one other alpha-olefin in contact under fluidized-bed polymerization or copolymerization conditions and/or stirred mechanically, with a charge powder in the presence of a catalyst comprising a chromium oxide compound associated with a granular support and activated by thermal treatment, this catalyst being used in the form of a prepolymer, this process being characterized in that the charge powder employed is previously subjected to a treatment by contacting the said charge powder with an organo- aluminium compound, in such a way that the polymerization or copolymerization starts up immediately after the contacting of the ethylene and optionally one other alpha-olefin with the charge powder in the presence of the prepolymer.
机译:本发明涉及通过在流化床聚合或共聚条件和/或条件下使乙烯和任选的至少一种其他α-烯烃接触来启动乙烯的聚合或乙烯与至少一种其他α-烯烃的共聚的方法。或在装料粉存在催化剂的情况下与装料粉一起机械搅拌或机械搅拌,该催化剂包含与粒状载体结合并通过热处理活化的氧化铬化合物,该催化剂以预聚物的形式使用,该方法的特征在于装料粉通过使所述装料粉末与有机铝化合物接触,预先对所使用的装料进行处理,使得在乙烯和任选的一种其他α-烯烃与装料粉末接触后立即开始聚合或共聚。预聚物的存在。

著录项

  • 公开/公告号US5075395A

    专利类型

  • 公开/公告日1991-12-24

    原文格式PDF

  • 申请/专利权人 BP CHEMICALS LIMITED;

    申请/专利号US19880157169

  • 申请日1988-02-11

  • 分类号C08F2/34;C08F10/02;

  • 国家 US

  • 入库时间 2022-08-22 05:23:34

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