Compounds of the formula ##STR1## and salts thereof, wherein R. sub.1 is hydrogen, chloro, bromo, carboxy or sulfo,PPR. sub.2 is hydrogen or C.sub.1-4 alkyl,PPR.sub.3 is hydrogen, C.sub. 1-4 alkyl or C.sub.1-4 hydroxyalkyl, andP PR.sub.4 is C. sub.1-6 alkyl monosubstituted by carboxy or sulfo; C. sub.2-6 alkyl monosubstituted by hydroxy or --OR.sub.5 ; C.sub.2-6 dihydroxyalkyl the hydroxy groups of which are on different carbon atoms; phenyl or phenyl monosubstituted or disubstituted by C.sub.1-4 alkyl, PP wherein R.sub.5 is C.sub.2-4 hydroxyalkyl, with the proviso that when each of R.sub.1, R.sub.2 and R.sub.3 is hydrogen, R.sub. 4 is other than 2- hydroxyethyl, and mixtures of such complexes and salts, useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, for example leather and fiber materials containing or consisting of natural or synthetic polyamides or of natural or regenerated cellulose, preferably textile material containing or consisting of cotton.
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机译:式## STR1 ##的化合物及其盐,其中R.sub.1是氢,氯,溴,羧基或磺基。 sub.2是氢或C 1-4烷基,P 3是氢。 P 1-4烷基或C 1-4羟烷基,和P 4 R 4是被羧基或磺基单取代的C 1-6烷基; C.sub.2-6被羟基或-OR.sub.5单取代的烷基; C 2-6二羟基烷基,其羟基在不同的碳原子上;苯基或被C 1-4烷基单取代或二取代的苯基,其中R 5是C 2-4羟烷基,条件是当每个R 1 ,R 2和R 3是氢,R 2是氢。 4不是2-羟乙基,以及这些络合物和盐的混合物,可用于染色或印刷含羟基或氮的有机底物,例如含有天然或合成聚酰胺或天然或再生聚酰胺或由其组成的皮革和纤维材料纤维素,最好是包含棉或由棉组成的纺织材料。
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