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Process for the preparation of a catalytic Support gamma Alumina with high thermal stability

机译:具有高热稳定性的催化载体γ-氧化铝的制备方法

摘要

The present Invention relates to a process for the preparation of a catalyst support of gamma Alumina with high thermal stabilityA composition which is expressed by the following: mxa1203 and H20 where M is one or more of the elements of the family of the lanthanides and / or Rare EarthsOr the first of a series of Transition Metals and / or Series of the Alkaline Earth Metals,All of the periodic table; "X" stands for the molar fraction in weight between 3 percent and 15 percent,Preferably between 3 and 10% and the Water content varies between 1 and 2 molar ratio.Characterized in that it comprises the steps of: Dewatering of a support base and a oxidohidru00f3xido aluminium Aluminium trihydroxide at a temperature of between 400 and 500 degrees C; to incorporate the SOPRotate amino salts with a ratio to 10 percent by weight of Alumina precursor, but can be increased up to 30 Weight percent, if they require additional Crystalline phases,Mix the two phases.The Solid Support with Concentrated aqueous solution of salts of polyvalent cations by vigorous shaking of the suspension or in the form of incipient Impregnation during 1 to 12 hHours at room temperatureDry the mixture formed between 90 and 110 deg C for 5 to 12 hours and calcinarla in oxidizing atmosphere at temperatures between 200 and 1100 deg C for a period of time greater than 4 hours.
机译:本发明涉及一种具有高热稳定性的γ-氧化铝催化剂载体的制备方法,其组成如下:mxa1203和H2O,其中M是镧系和/或镧系元素的一个或多个。或稀土元素或一系列过渡金属和/或一系列碱土金属中的第一个,所有元素周期表; “ X”代表重量的摩尔分数在3%至15%之间,优选在3%至10%之间,并且水含量在1至2摩尔比之间变化。其特征在于它包括以下步骤:载体的脱水碱和在400至500摄氏度之间的氧化氢氧化铝铝氢氧化铝;掺入SOPRotate氨基盐的比例为氧化铝前体重量的10%,但如果需要额外的结晶相,则可以增加至30 wt%,将这两个相混合。在室温下1到12小时内剧烈振荡悬浮液或以初期浸渍的形式形成多价阳离子;在90到110摄氏度之间干燥形成的混合物5到12个小时;在氧化气氛中在200到1100摄氏度之间的温度下干燥钙硅铝持续时间超过4小时。

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