Chiral metallocene compounds and preparation thereof by means of the creation of a Chiral Centre for transfer of hidruroenantioselectiva

摘要

Coordinators provide groups of ciclopentadienilo substituted Chiral enantiomu00e9ricamente improved, and compounds thereof,And a process for its production, which comprises contacting a fulveno optionally replaced with a prochiral carbon Atom 6 with a Lithium Salt of an amineAmino Acid or amide for the Enantioselective addition of HYDRIDE at the carbon atom of the fulveno 6 to create a Chiral Centre.They also provide improved enantiomu00e9ricamente Chiral organometallic complexes with one or More groups of ciclopentadienilo substituted Chiral.